Kinetic and Mechanistic Study of the Reaction of Atomic Chlorine with Methyl Iodide over the Temperature Range 218−694 K

1997 ◽  
Vol 101 (49) ◽  
pp. 9382-9390 ◽  
Author(s):  
Y. V. Ayhens ◽  
J. M. Nicovich ◽  
M. L. McKee ◽  
P. H. Wine
Keyword(s):  
Methyl Iodide ◽  
Mechanistic Study ◽  
Temperature Range ◽  
Atomic Chlorine

Kinetic and mechanistic study of the reaction of atomic chlorine with methyl bromide over an extended temperature range

1998 ◽  
Vol 231 (2-3) ◽  
pp. 155-169 ◽  
Author(s):  
C.A. Piety ◽  
R. Soller ◽  
J.M. Nicovich ◽  
M.L. McKee ◽  
P.H. Wine
Keyword(s):  
Methyl Bromide ◽  
Mechanistic Study ◽  
Temperature Range ◽  
Atomic Chlorine

Kinetic and Mechanistic Study of the Reaction of Atomic Chlorine with Dimethylsulfide

1993 ◽  
pp. 243-249
Author(s):  
R. E. Stickel ◽  
J. M. Nicovich ◽  
S. Wang ◽  
Z. Zhao ◽  
P. H. Wine
Keyword(s):  
Mechanistic Study ◽  
Atomic Chlorine

Kinetic and Mechanistic Study of the Reactions of Atomic Chlorine with CH3CH2Br, CH3CH2CH2Br, and CH2BrCH2Br

2011 ◽  
Vol 115 (9) ◽  
pp. 1658-1666 ◽  
Author(s):  
Patrick L. Laine ◽  
J. Michael Nicovich ◽  
Paul H. Wine
Keyword(s):  
Mechanistic Study ◽  
Atomic Chlorine

Excess thermodynamic properties of the liquid system acetone + methyl iodide

1964 ◽  
Vol 281 (1386) ◽  
pp. 366-376 ◽  
Keyword(s):  
Free Energy ◽  
Thermodynamic Properties ◽  
Methyl Iodide ◽  
Excess Entropy ◽  
Heat Content ◽  
Liquid Mixtures ◽  
Liquid System ◽  
Excess Thermodynamic Properties ◽  
Temperature Range ◽  
Entropy Of Mixing

The increase in heat content attending the isobaric formation of liquid mixtures of acetone and methyl iodide in varying proportions has been determined calorimetrically in the temperature range 253 to 308 °K. The corresponding change in free energy has been measured from analyses of the mixed vapour at equilibrium with the mixed liquids. By difference, the change in entropy associated with the mixing has been found. Most of this derives, as is usual, from the randomness of the mixture, but there is a relatively small residuum (the so-called excess entropy of mixing) which is found to vary in an unusual way with respect to the composition.

Kinetic and mechanistic study of the reaction of atomic chlorine with dimethyl sulfide

1992 ◽  
Vol 96 (24) ◽  
pp. 9875-9883 ◽  
Author(s):  
R. E. Stickel ◽  
J. M. Nicovich ◽  
S. Wang ◽  
Z. Zhao ◽  
P. H. Wine
Keyword(s):  
Dimethyl Sulfide ◽  
Mechanistic Study ◽  
Atomic Chlorine
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