Characterization of Silica-Supported Pd−Au Clusters by X-ray Absorption Spectroscopy

1999 ◽  
Vol 103 (2) ◽  
pp. 321-329 ◽  
Author(s):  
Scott N. Reifsnyder ◽  
H. Henry Lamb
1995 ◽  
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pp. 343-346 ◽  
Author(s):  
John M. Charnock ◽  
C. David Garner ◽  
Alfred X. Trautwein ◽  
Eckard Bill ◽  
Heiner Winkler ◽  
...  

Wear ◽  
1997 ◽  
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pp. 172-191 ◽  
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Zhanfeng Yin ◽  
Masoud Kasrai ◽  
Marina Fuller ◽  
G.Michael Bancroft ◽  
Kim Fyfe ◽  
...  

1988 ◽  
Vol 127 ◽  
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R. B. Greegor ◽  
F. W. Lytle ◽  
B. C. Chakoumakos ◽  
G. R. Lumpkin ◽  
J. K. Warner ◽  
...  

ABSTRACTX-ray absorption spectroscopy has been used to investigate the Nb B-site in pyrochlores (A1.2B2O6Y0–1, Fd3m, Z=8) and samarskites (A3B5O16) in both metamict and annealed condition. The XANES and EXAFS measurements indicate significant changes in pyrochlore and smaller changes in samarskite as a result of radiation damage. In the metamict state the Nb site in both pyrochlores and samarskites is similar to Nb in Nb2O5. Short Nb-O (1.65Å) bonds are not disrupted by alpha-decay/recoil-nuclei events as much as longer bonds (2.00Å). This increases the asymmetry and static disorder at the local Nb site while long range order is greatly diminished resulting in considerable distribution in Nb-M distances and bond angles.


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