Photoisomerization Reaction of Unsymmetrical Azobenzene Disulfide Self-Assembled Monolayers Studied by Surface Plasmon Spectroscopy:  Influences of Side Chain Length and Contacting Medium

Langmuir ◽  
2002 ◽  
Vol 18 (13) ◽  
pp. 5239-5246 ◽  
Author(s):  
Kaoru Tamada ◽  
Haruhisa Akiyama ◽  
Tian Xin Wei
1997 ◽  
Vol 101 (16) ◽  
pp. 3174-3180 ◽  
Author(s):  
Timothy T. Ehler ◽  
Nathan Malmberg ◽  
Keith Carron ◽  
B. Patrick Sullivan ◽  
Lewis J. Noe

Langmuir ◽  
2017 ◽  
Vol 33 (49) ◽  
pp. 13936-13944 ◽  
Author(s):  
Zhijun Li ◽  
Kim Munro ◽  
Iraklli I. Ebralize ◽  
Mina R. Narouz ◽  
J. Daniel Padmos ◽  
...  

2011 ◽  
Vol 115 (36) ◽  
pp. 17788-17798 ◽  
Author(s):  
María Alejandra Floridia Addato ◽  
Aldo A. Rubert ◽  
Guillermo A. Benítez ◽  
Mariano H. Fonticelli ◽  
Javier Carrasco ◽  
...  

2012 ◽  
Vol 3 ◽  
pp. 12-24 ◽  
Author(s):  
Hicham Hamoudi ◽  
Ping Kao ◽  
Alexei Nefedov ◽  
David L Allara ◽  
Michael Zharnikov

Self-assembled monolayers (SAMs) of nitrile-substituted oligo(phenylene ethynylene) thiols (NC-OPEn) with a variable chain length n (n ranging from one to three structural units) on Au(111) were studied by synchrotron-based high-resolution X-ray photoelectron spectroscopy and near-edge absorption fine-structure spectroscopy. The experimental data suggest that the NC-OPEn molecules form well-defined SAMs on Au(111), with all the molecules bound to the substrate through the gold–thiolate anchor and the nitrile tail groups located at the SAM–ambient interface. The packing density in these SAMs was found to be close to that of alkanethiolate monolayers on Au(111), independent of the chain length. Similar behavior was found for the molecular inclination, with an average tilt angle of ~33–36° for all the target systems. In contrast, the average twist of the OPEn backbone (planar conformation) was found to depend on the molecular length, being close to 45° for the films comprising the short OPE chains and ~53.5° for the long chains. Analysis of the data suggests that the attachment of the nitrile moiety, which served as a spectroscopic marker group, to the OPEn backbone did not significantly affect the molecular orientation in the SAMs.


2004 ◽  
Vol 120 (8) ◽  
pp. 3880-3886 ◽  
Author(s):  
A. W. Rosenbaum ◽  
M. A. Freedman ◽  
S. B. Darling ◽  
I. Popova ◽  
S. J. Sibener

Nano Letters ◽  
2006 ◽  
Vol 6 (11) ◽  
pp. 2617-2621 ◽  
Author(s):  
Carly S. Levin ◽  
Benjamin G. Janesko ◽  
Rizia Bardhan ◽  
Gustavo E. Scuseria ◽  
Jeffrey D. Hartgerink ◽  
...  

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