A Highly Efficient Initiator for the Ring-Opening Polymerization of Lactides and ε-Caprolactone:  A Kinetic Study

Ring-opening polymerization (ROP) of lactones catalyzed by 1,5,7-triazabicyclo[4,4,0]decane-5-ene (TBD) is a highly efficient method for synthesizing aliphatic polyester materials. In order to create a green and sustainable synthetic route of...

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Ring opening polymerization of l-lactide by an electron-rich Schiff base zinc complex: An activity and kinetic study

Journal of Molecular Catalysis A Chemical ◽

10.1016/j.molcata.2011.10.012 ◽

2012 ◽

Vol 352 ◽

pp. 57-62 ◽

Cited By ~ 12

Author(s):

Lihui Yao ◽

Lei Wang ◽

Jinfeng Zhang ◽

Ning Tang ◽

Jincai Wu

Keyword(s):

Schiff Base ◽

Kinetic Study ◽

Ring Opening ◽

Zinc Complex ◽

Ring Opening Polymerization

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Highly efficient catalysts-acetylacetonato complexes of transition metals in the 4th period for ring-opening polymerization of 1,3-benzoxazine

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/pola.23810 ◽

2009 ◽

Vol 48 (2) ◽

pp. 479-484 ◽

Cited By ~ 85

Author(s):

Atsushi Sudo ◽

Shoji Hirayama ◽

Takeshi Endo

Keyword(s):

Transition Metals ◽

Ring Opening ◽

Ring Opening Polymerization ◽

Highly Efficient ◽

Complexes Of Transition Metals

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Highly Efficient Aluminum-Catalyzed Ring-Opening Polymerization of Cyclic Carbonates, Lactones, and Lactides, Including a Unique Crystallographic Snapshot of an Intermediate

Organometallics ◽

10.1021/om2003283 ◽

2011 ◽

Vol 30 (11) ◽

pp. 3217-3224 ◽

Cited By ~ 41

Author(s):

Jürgen Koller ◽

Robert G. Bergman

Keyword(s):

Ring Opening ◽

Ring Opening Polymerization ◽

Cyclic Carbonates ◽

Highly Efficient

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Highly efficient ring‐opening polymerization of tetrahydrofuran by anhydrous ferric chloride

Journal of Applied Polymer Science ◽

10.1002/app.47999 ◽

2019 ◽

Vol 136 (39) ◽

pp. 47999 ◽

Cited By ~ 1

Author(s):

Hee Jung Yang ◽

Seok Won Yoon ◽

Hee Sun Park ◽

Kyu Hyung Lee ◽

Nam Hwi Hur

Keyword(s):

Ferric Chloride ◽

Ring Opening ◽

Ring Opening Polymerization ◽

Highly Efficient ◽

Anhydrous Ferric Chloride

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Structure and Activity Relationship Studies of N-Heterocyclic Olefins and Thioureas/Ureas Catalytic System: Application in Ring-opening Polymerization of Lactones

Polymer Chemistry ◽

10.1039/d0py01747g ◽

2021 ◽

Author(s):

Li Zhou ◽

Zhenyu Wang ◽

Guangqiang Xu ◽

Chengdong Lv ◽

Qinggang Wang

Keyword(s):

Catalytic System ◽

System Application ◽

Ring Opening ◽

Ring Opening Polymerization ◽

Activity Relationship ◽

Highly Efficient ◽

Structure And Activity

A highly efficient and controllable ring-opening polymerization of lactones (δ-valerolactone, ε-caprolactone and rac-lactide) has been achieved by using N-heterocyclic olefins (NHOs) and thioureas/ureas (TUs/Us) catalytic system. This catalytic system showed...

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