Atom-Economical Synthesis of the N(10)−C(17) Fragment of Cyclotheonamides via a Novel Passerini Reaction−Deprotection−Acyl Migration Strategy1

2001 ◽  
Vol 3 (21) ◽  
pp. 3301-3304 ◽  
Author(s):  
Timothy D. Owens ◽  
J. Edward Semple
Keyword(s):  
Acyl Migration ◽  
Passerini Reaction

Passerini Reaction−Amine Deprotection−Acyl Migration Peptide Assembly: Efficient Formal Synthesis of Cyclotheonamide C

2009 ◽  
Vol 11 (5) ◽  
pp. 1167-1170 ◽  
Author(s):  
Sophie Faure ◽  
Thomas Hjelmgaard ◽  
Stéphane P. Roche ◽  
David J. Aitken
Keyword(s):  
Acyl Migration ◽  
Passerini Reaction ◽  
Formal Synthesis ◽  
Peptide Assembly

Acyl-migration Occurence of Palm Oil During Interesterfication Catalyzed by Sn-1,3 Specific Lipase

2020 ◽  
Author(s):  
Yong Wang ◽  
Haiyan Zhou ◽  
Aijun Li ◽  
Zhen Zhang ◽  
Wan Jun Lee
Keyword(s):  
Palm Oil ◽  
Acyl Migration

scholarly journals Keto-Enol Tautomerism in Passerini and Ugi Adducts

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 919
Author(s):  
Pablo Pertejo ◽  
Andrea Sancho-Medina ◽  
Tomás Hermosilla ◽  
Beatriz González-Saiz ◽  
Javier Gómez-Ayuso ◽  
...  
Keyword(s):  
Starting Material ◽  
Passerini Reaction ◽  
The Way

The use of arylglyoxal as starting material in Passerini and Ugi reactions affords β-ketoamides. This has allowed to study keto-enol tautomerism in these systems and assess the way in which the presence of acyloxy or aminoacyl groups bound to the C2 position affects such tautomerism, and to investigate the reactivity of both the enol and carbonyl forms. In this work we also prove the versatility of the Passerini reaction, since depending on the conditions to which the corresponding adducts are subjected different products of synthetic interest can be obtained.

C(sp3)–H Functionalization with Isocyanides

2021 ◽  
Author(s):  
Weixiang Wang ◽  
Tianqi Liu ◽  
Chang-Hua Ding ◽  
Bin Xu
Keyword(s):  
Functional Group ◽  
Ugi Reaction ◽  
Atom Economy ◽  
Passerini Reaction

Isocyanide is well known for its multi-component reactions (MCR), such as Passerini reaction and Ugi reaction, with diverse molecular skeletons, high functional group compatibility, and good atom economy. With the...

24. Acyl migration during dephosphorylation and a suggested mechanism

1953 ◽  
pp. 127 ◽  
Author(s):  
T. H. Bevan ◽  
D. A. Brown ◽  
G. I. Gregory ◽  
T. Malkin
Keyword(s):  
Acyl Migration
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