Advances in Lewis Acid Controlled Carbon−Carbon Bond-Forming Reactions Enable a Concise and Convergent Total Synthesis of Bullatacin

2006 ◽  
Vol 8 (19) ◽  
pp. 4379-4382 ◽  
Author(s):  
Hongda Zhao ◽  
Jeffrey S. T. Gorman ◽  
Brian L. Pagenkopf
Keyword(s):  
Total Synthesis ◽  
Lewis Acid ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions

Lewis-acid catalysis of carbon carbon bond forming reactions in water

1996 ◽  
Vol 115 (11-12) ◽  
pp. 457-464 ◽  
Author(s):  
Jan B. F. N. Engberts ◽  
Ben L. Feringa ◽  
Erik Keller ◽  
Sijbren Otto
Keyword(s):  
Lewis Acid ◽  
Acid Catalysis ◽  
Lewis Acid Catalysis ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions

scholarly journals Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective

2017 ◽  
Vol 13 ◽  
pp. 2214-2234 ◽  
Author(s):  
Yaroslav Dmitrievich Boyko ◽  
Valentin Sergeevich Dorokhov ◽  
Alexey Yu Sukhorukov ◽  
Sema Leibovich Ioffe
Keyword(s):  
Total Synthesis ◽  
Organic Synthesis ◽  
Michael Addition ◽  
High Reactivity ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions ◽  
Recent Developments ◽  
Michael Acceptors

Despite of their chemical instability and high reactivity, conjugated nitrosoalkenes are useful intermediates in target-oriented organic synthesis. The present review deals with carbon–carbon bond forming reactions involving Michael addition to α-nitrosoalkenes with a particular focus on recent developments in this methodology and its use in total synthesis.

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