Copper-Catalyzed β-Boration of α,β-Unsaturated Carbonyl Compounds:  Rate Acceleration by Alcohol Additives†

A mixed-design experiment was conducted to explore differences between searching and surfing on cognitive and emotional responses to online news. Ninety-two participants read three unpleasant news stories from a website. Half of the participants acquired their stories by searching, meaning they had a previous information need in mind. The other half of the participants acquired their stories by surfing, with no previous information need in mind. Heart rate, skin conductance, and corrugator activation were collected as measures of resource allocation, motivational activation, and unpleasantness, respectively, while participants read each story. Self-report valence and recognition accuracy were also measured. Stories acquired by searching elicited greater heart rate acceleration, skin conductance level, and corrugator activation during reading. These stories were rated as more unpleasant, and their details were recognized more accurately than similar stories that were acquired by surfing. Implications of these results for understanding how people process online media are discussed.

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The reduction of α,β-unsaturated carbonyl compounds by the meerwein—ponndorf—verley method: The cause of low yields

Journal of Applied Chemistry and Biotechnology ◽

10.1002/jctb.5020220404 ◽

1972 ◽

Vol 22 (4) ◽

pp. 465-474 ◽

Cited By ~ 2

Author(s):

J. H. P. Tyman

Keyword(s):

Carbonyl Compounds

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Silicon Assisted Sulfuration: Tetrachlorosilane-Sodium Sulfide-A New Potent Thionating Reagent for Carbonyl Compounds

10.3390/ecsoc-11-01317 ◽

2007 ◽

Author(s):

T. A. Salama ◽

S. S. Elmorsy ◽

A. M. Khalil ◽

M. A. Ismail ◽

A. S. El-Ahl

Keyword(s):

Carbonyl Compounds ◽

Sodium Sulfide

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A FACILE SYNTHESIS AND REACTIONS OF AMINO SELENOLO[2,3-b]PYRIDINE CARBOXYLATE

JOURNAL OF ADVANCES IN CHEMISTRY ◽

10.24297/jac.v12i1.845 ◽

2015 ◽

Vol 12 (1) ◽

pp. 3910-3918 ◽

Cited By ~ 1

Author(s):

Dr Remon M Zaki ◽

Prof Adel M. Kamal El-Dean ◽

Dr Nermin A Marzouk ◽

Prof Jehan A Micky ◽

Mrs Rasha H Ahmed

Keyword(s):

Biological Activity ◽

Carbonyl Compounds ◽

Mass Spectra ◽

The Other ◽

Pyridine Derivatives ◽

Facile Synthesis ◽

High Biological Activity ◽

Basic Hydrolysis ◽

Pyridine Carboxylate ◽

Hydrolysis Of

Incorporating selenium metal bonded to the pyridine nucleus was achieved by the reaction of selenium metal with 2-chloropyridine carbonitrile 1 in the presence of sodium borohydride as reducing agent. The resulting non isolated selanyl sodium salt was subjected to react with various α-halogenated carbonyl compounds to afford the selenyl pyridine derivatives 3a-f which compounds 3a-d underwent Thorpe-Ziegler cyclization to give 1-amino-2-substitutedselenolo[2,3-b]pyridine compounds 4a-d, while the other compounds 3e,f failed to be cyclized. Basic hydrolysis of amino selenolo[2,3-b]pyridine carboxylate 4a followed by decarboxylation furnished the corresponding amino selenolopyridine compound 6 which was used as a versatile precursor for synthesis of other heterocyclic compound 7-16. All the newly synthesized compounds were established by elemental and spectral analysis (IR, 1H NMR) in addition to mass spectra for some of them hoping these compounds afforded high biological activity.

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Directed, Palladium(II)-Catalyzed Enantioselective anti-Carboboration of Alkenyl Carbonyl Compounds

10.26434/chemrxiv.7577597.v1 ◽

2019 ◽

Author(s):

Zhen Liu ◽

Xiaohan Li ◽

Tian Zeng ◽

Keary Engle

Keyword(s):

Carbonyl Compounds ◽

Building Blocks ◽

New Method ◽

Carbon Based

A substrate-directed enantioselective anti-carboboration reaction of alkenes has been developed, wherein a carbon based nucleophile and a boron moiety are installed across the C=C bond through a 5- or 6-membered palladacycle intermediate. The reaction is promoted by a palladium(II) catalyst and a mondentate oxzazoline ligand. A range of enantioenriched secondary alkylboronate products were obtained with moderate to high enantioselectivity that could be further upgraded by recrystallization. This work represents a new method to synthesize versatile and valuable alkylboronate building blocks. Building on an earlier mechanistic proposal by Peng, He, and Chen, a revised model is proposed to account for the stereoconvergent nature of this transformation.

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Tetranuclear Copper and Mononuclear Nickel Complex of the Schiff Base of (3Z)-3-Hydrazonobutan-2-One Oxime with Different Aromatic Carbonyl Compounds: Synthesis, Single Crystal X-Ray Structure, Catecholase Activity, Phenoxazinone Synthase Activity, Catalytic Study for the Homocoupling of Benzyl Amines

10.26434/chemrxiv.9632036.v1 ◽

2019 ◽

Author(s):

Swaraj Sengupta ◽

Sahanwaj Khan ◽

Shyamal K. Chattopadhyay ◽

Indrani Banerjee ◽

Tarun K. Panda ◽

...

Keyword(s):

Schiff Base ◽

Single Crystal ◽

Copper Complex ◽

Carbonyl Compounds ◽

Nickel Complex ◽

Schiff Base Ligands ◽

X Ray ◽

Phenoxazinone Synthase ◽

Catecholase Activity ◽

Aromatic Carbonyl Compounds

Synthesis and characterisation of one trinuclear copper complex, ([Cu3L3O]ClO4) (1) and one nickel complex ([Ni(L'H)2(dmso)2](ClO4)2) (2) with Schiff base ligands: (3Z)-3-((Z)-(1-(thiophen-2-yl)ethylidene)hydrazono)butan-2-one oxime (LH) and 1-(pyridin-2-yl)ethylidene)hydrazono)butan-2-one oxime (L'H). 1 shows high catecholase activity and has also been tested as a catalyst for the synthesis of benzylimine. 2 shows phenoxazinone synthase activity.

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