Approach to the Tricyclic Core of the Tigliane–Daphnane Diterpenes. Concerning the Utility of Transannular Aldol Additions

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Stereoselective construction of the highly oxygenated decahydrocyclopenta[g]chromene skeleton, the tricyclic core of leucosceptrine and leucosesterterpenone, from Leucosceptrum canum, was achieved.


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