Total Syntheses of Enokipodins A and B Utilizing Palladium-Catalyzed Addition of An Arylboronic Acid to An Allene

2009 ◽  
Vol 11 (6) ◽  
pp. 1441-1443 ◽  
Author(s):  
Masahiro Yoshida ◽  
Yasunobu Shoji ◽  
Kozo Shishido
Keyword(s):  
Arylboronic Acid ◽  
Total Syntheses ◽  
Palladium Catalyzed

Formal Total Syntheses of Crocacin A-D

2005 ◽  
Vol 70 (10) ◽  
pp. 1696-1708 ◽  
Author(s):  
Magnus Besev ◽  
Christof Brehm ◽  
Alois Fürstner
Keyword(s):  
Natural Products ◽  
Aldol Reaction ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Total Syntheses ◽  
Cross Coupling Reactions ◽  
Palladium Catalyzed ◽  
The Common ◽  
Selective Addition

A concise route to the common polyketide fragment5of crocacin A-D (1-4) is presented which has previously been converted into all members of this fungicidal and cytotoxic family of dipeptidic natural products by various means. Our synthesis features asyn-selective titanium aldol reaction controlled by a valinol-derived auxiliary, a zinc-mediated, palladium-catalyzedanti-selective addition of propargyl mesylate10to the chiral aldehyde9, as well as a comparison of palladium-catalyzed Stille and Suzuki cross-coupling reactions for the formation of the diene moiety of the target.

Total Syntheses of Prothracarcin and Tomaymycin by Use of Palladium Catalyzed Carbonylation

Tetrahedron ◽  
1986 ◽  
Vol 42 (14) ◽  
pp. 3793-3806 ◽  
Author(s):  
Miwako Mori ◽  
Yasuhiro Uozumi ◽  
Masaya Kimura ◽  
Yoshio Ban
Keyword(s):  
Total Syntheses ◽  
Palladium Catalyzed

Enantioselective Total Syntheses of Lyconadins A–E through a Palladium‐Catalyzed Heck‐Type Reaction

2020 ◽  
Vol 59 (7) ◽  
pp. 2860-2866 ◽  
Author(s):  
Jiayang Zhang ◽  
Yangtian Yan ◽  
Rong Hu ◽  
Ting Li ◽  
Wen‐Ju Bai ◽  
...  
Keyword(s):  
Total Syntheses ◽  
Type Reaction ◽  
Palladium Catalyzed

Palladium-catalyzed fluoroacylation of (Hetero)arylboronic acid with fluorothioacetates at ambient temperature

2020 ◽  
Vol 61 (16) ◽  
pp. 151780
Author(s):  
Xing Yi ◽  
Ya-Fang Cao ◽  
Xing Wang ◽  
Hui Xu ◽  
Shu-Rong Ban ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Arylboronic Acid ◽  
Palladium Catalyzed

Enantioselective Total Syntheses of Lyconadins A–E through a Palladium‐Catalyzed Heck‐Type Reaction

2020 ◽  
Vol 132 (7) ◽  
pp. 2882-2888 ◽  
Author(s):  
Jiayang Zhang ◽  
Yangtian Yan ◽  
Rong Hu ◽  
Ting Li ◽  
Wen‐Ju Bai ◽  
...  
Keyword(s):  
Total Syntheses ◽  
Type Reaction ◽  
Palladium Catalyzed
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