Study of metal-ligand multiple bonding in osmium and iridium imido complexes: evidence for the cyclopentadienyl-imido analogy

1992 ◽  
Vol 11 (12) ◽  
pp. 4221-4225 ◽  
Author(s):  
David S. Glueck ◽  
Jennifer C. Green ◽  
Richard I. Michelman ◽  
Ian N. Wright
Keyword(s):  
Multiple Bonding ◽  
Imido Complexes ◽  
Metal Ligand

Metal–ligand multiple bonding in uranium: structure and reactivity

2010 ◽  
Vol 39 (5) ◽  
pp. 1145-1158 ◽  
Author(s):  
Trevor W. Hayton
Keyword(s):  
Multiple Bonding ◽  
Metal Ligand

Multiple Bonding in Lanthanides and Actinides: Direct Comparison of Covalency in Thorium(IV)- and Cerium(IV)-Imido Complexes

2019 ◽  
Vol 141 (23) ◽  
pp. 9185-9190 ◽  
Author(s):  
Thibault Cheisson ◽  
Kyle D. Kersey ◽  
Nolwenn Mahieu ◽  
Alex McSkimming ◽  
Michael R. Gau ◽  
...  
Keyword(s):  
Multiple Bonding ◽  
Imido Complexes

scholarly journals Metal-ligand ``multiple`` bonding: Revelations in the electronic structure of complexes of high-valent f-elements

1997 ◽  
Author(s):  
C.J. Burns ◽  
D.S.J. Arney ◽  
R.C. Schnabel ◽  
B.P. Warner ◽  
B.E. Bursten ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Multiple Bonding ◽  
High Valent ◽  
Metal Ligand

scholarly journals Charge control of the inverse trans-influence

2015 ◽  
Vol 51 (93) ◽  
pp. 16671-16674 ◽  
Author(s):  
Henry S. La Pierre ◽  
Michael Rosenzweig ◽  
Boris Kosog ◽  
Christina Hauser ◽  
Frank W. Heinemann ◽  
...  
Keyword(s):  
Ground State ◽  
Charge Control ◽  
Charge Localization ◽  
Multiple Bonding ◽  
Trans Influence ◽  
Multiply Bonded ◽  
Metal Ligand

The relative charge localization on the multiply bonded ligand (O2− or TMSN2−) governs the ground state stabilization derived from the inverse trans-influence (ITI) in U(vi) complexes of the [((RArO)3tacn)UL]+ system with metal-ligand multiple bonding (MLMB).

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