Mechanistic study of the reactions of 1,1-dimethylallene with nickel(0) complexes. The .pi.- and .sigma.-complex formation vs. electron transfer

1985 ◽  
Vol 4 (8) ◽  
pp. 1386-1395 ◽  
Author(s):  
Daniel J. Pasto ◽  
Nai Zhong. Huang

1987 ◽  
Vol 52 (7) ◽  
pp. 1658-1665
Author(s):  
Viktor Řehák ◽  
Jana Boledovičová

Disodium 1,5- and 1,8-anthracenedisulphonate (ADS) and 9-acetylanthracene form coloured CT complexes with methylviologen (MV2+) in aqueous and micellar media. The complex formation constants and molar absorptivities were determined by the Benesi-Hildebrandt method. In the fluorescence quenching, its static component plays the major role. The dynamic quenching component is determined by the rate constant of electron transfer from the S1 state of ADS to MV2+.







2010 ◽  
Vol 110 (12) ◽  
pp. PR1-PR40 ◽  
Author(s):  
Cyrille Costentin ◽  
Marc Robert ◽  
Jean-Michel Savéant




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