Organic Synthesis via Transition Metal Complexes. 112.1Reactivity Enhancement of Group VI Fischer Carbene Complexes by Copper and Rhodium Catalysts:  Experimental Proof of a Carbene Rhodium Complex as an Intermediate

2001 ◽  
Vol 20 (16) ◽  
pp. 3574-3581 ◽  
Author(s):  
Inigo Göttker-Schnetmann ◽  
Rudolf Aumann ◽  
Klaus Bergander
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Organic Synthesis ◽  
Transition Metal Complexes ◽  
Rhodium Complex ◽  
Fischer Carbene Complexes ◽  
Group Vi ◽  
Experimental Proof ◽  
Carbene Complexes ◽  
Fischer Carbene

scholarly journals The steric and electronic effects of metal-containing substituents on Fischer carbene metal clusters

2009 ◽  
Vol 28 (3) ◽  
pp. 237-260
Author(s):  
Editorial Office
Keyword(s):  
Carbon Atom ◽  
Transition Metal ◽  
Metal Clusters ◽  
Electronic Effects ◽  
Fischer Carbene Complexes ◽  
Group Vi ◽  
Carbene Complexes ◽  
Fischer Carbene

Novel Group VI transition metal Fischer carbene complexes containing three different transition metal substituents, all in electronic contact with the carbene carbon atom, were synthesised.

Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Carbene Complexes ◽  
New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

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