A New Class of Constrained-Geometry Metallocenes:  Synthesis and Crystal Structure of a Carboranyl−Thiol-Appended Half-Sandwich Titanocene and Its Conversion to Halotitanocene

2003 ◽  
Vol 22 (24) ◽  
pp. 4839-4841 ◽  
Author(s):  
Jianhui Wang ◽  
Chong Zheng ◽  
John A. Maguire ◽  
Narayan S. Hosmane
Keyword(s):  
Crystal Structure ◽  
Synthesis And Crystal Structure ◽  
New Class ◽  
Constrained Geometry ◽  
Half Sandwich

scholarly journals Synthesis and crystal structure oftrans-dichlorido[3-methyl-1-(4-vinylbenzyl)-1H-imidazol-3-ium-2-yl-κC2](4-phenylpyridine-κN)palladium(II)

2016 ◽  
Vol 72 (4) ◽  
pp. 534-537 ◽  
Author(s):  
Maitham H. Majeed ◽  
Ola F. Wendt
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Pyridine Ring ◽  
Imidazole Ring ◽  
Planar Geometry ◽  
Synthesis And Crystal Structure ◽  
New Class ◽  
Centroid Distance ◽  
Square Planar ◽  
Catalytically Active

The title compound, [PdCl2(C11H9N)(C13H14N2)], represents a new class of palladium-based polymerizable monomer which could give a potentially catalytically active polymer. It was synthesizedviatransmetallation from the corresponding silver complex. The PdIIion coordinates two Cl anions, one C atom from the N-heterocyclic carbene (NHC) ligand and one N atom from the 4-phenylpyridine ligand, displaying a slightly distorted square-planar geometry. The dihedral angle between the imidazole ring and the pyridine ring is 34.53 (8)°. The Pd—C bond length between the NHC ligand and the PdIIion is 1.9532 (16) Å. In the crystal, weak non-classical C—H...Cl hydrogen bonds link the molecules into a tape structure along [101]. A weak π–π interaction is also observed [centroid–centroid distance = 3.9117 (11) Å].

Synthesis and crystal structure of [MnL(μ-Cl)MnCl3]·H2O L=N, N'-bis(2'-pyridine)methyl-1,10-phenanthroline-2,9-dimethanamine

2002 ◽  
Vol 2002 (3) ◽  
pp. 120-121
Author(s):  
Tian Fu Liu ◽  
Hua Kuan Lin ◽  
Shou Rong Zhu ◽  
Zhong Ming Wang ◽  
Hong Gen Wang ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Synthesis And Crystal Structure

Synthesis and crystal structure of an 18-Mo girdle-like polyoxomolybdate

2002 ◽  
Vol 2002 (3) ◽  
pp. 107-109 ◽  
Author(s):  
Guang Liu ◽  
Jian Liu ◽  
Shi-Wei Zhang
Keyword(s):  
Crystal Structure ◽  
Synthesis And Crystal Structure

The Synthesis and Crystal Structure of Aluminum Selenite Trihydrate, Al2(seO3)3.32O

1992 ◽  
Author(s):  
W. T. Harrison ◽  
G. D. Stucky ◽  
R. E. Morris ◽  
A. K. Cheetham
Keyword(s):  
Crystal Structure ◽  
Synthesis And Crystal Structure
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