Thulium Alkylidene Complexes:  Synthesis, X-ray Structures, and Reactivity

Thibault Cantat; Florian Jaroschik; Louis Ricard; Pascal Le Floch; François Nief; Nicolas Mézailles

doi:10.1021/om050877c

Thulium Alkylidene Complexes: Synthesis, X-ray Structures, and Reactivity

Organometallics ◽

10.1021/om050877c ◽

2006 ◽

Vol 25 (5) ◽

pp. 1329-1332 ◽

Cited By ~ 78

Author(s):

Thibault Cantat ◽

Florian Jaroschik ◽

Louis Ricard ◽

Pascal Le Floch ◽

François Nief ◽

...

Keyword(s):

X Ray ◽

Alkylidene Complexes

Formation and Selective Trapping of 2,5-Dihydropyridine and Its Isopropylidene Derivative by Tungsten(0) Alkylidene Complexes. X-ray Structure of the 5-Isopropylidene-2,5-dihydropyridine Adduct

Organometallics ◽

10.1021/om9708079 ◽

1998 ◽

Vol 17 (3) ◽

pp. 361-366 ◽

Cited By ~ 12

Author(s):

Henri Rudler ◽

Blanca Martín-Vaca ◽

Muriel Nicolas ◽

Max Audouin ◽

Jacqueline Vaissermann

Keyword(s):

X Ray ◽

Isopropylidene Derivative ◽

Alkylidene Complexes

The synthesis and structure of Group 5 metal alkyl and alkylidene complexes containing 2,6-dialkylphenoxide ligands: X-ray crystal structures of [Ta(OC6H3Me2-2,6)2(CH2Ph)3], [Ta(OC6H3Me2-2,6)4Me], and [Ta(OC6H3But2-2,6)2(CHSiMe3)(CH2SiMe3)]

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9870000155 ◽

1987 ◽

pp. 155-162 ◽

Cited By ~ 29

Author(s):

Linda R. Chamberlain ◽

Ian P. Rothwell ◽

Kirsten Folting ◽

John C. Huffman

Keyword(s):

Crystal Structures ◽

X Ray ◽

Group 5 ◽

Alkylidene Complexes

Addition of small molecules to (.eta.-C5H5)2Rh2(CO)(CF3C2CF3). 6. Formation of the .mu.-alkylidene complexes (.eta.-C5H5)2Rh2(.mu.-CO)(.mu.-CHR)(.mu.-CF3C2CF3) (R = CO2Et, SiMe3, CF3, or CH:CH4) and coupling reactions of the alkyne and carbene ligands within these complexes. X-ray crystal structure of (.eta.-C5H5)2Rh2(CO){C(CF3)C(CF3)CH(CO2Et)}

Organometallics ◽

10.1021/om00149a020 ◽

1987 ◽

Vol 6 (6) ◽

pp. 1240-1246 ◽

Cited By ~ 11

Author(s):

Ron S. Dickson ◽

Gary D. Fallon ◽

Susan M. Jenkins ◽

Rhonda J. Nesbit

Keyword(s):

Crystal Structure ◽

Small Molecules ◽

Coupling Reactions ◽

Carbene Ligands ◽

X Ray ◽

Alkylidene Complexes

Multinuclear NMR Studies and Reaction with tert-Butyl Isocyanide of Dinuclear Tungsten- or Molybdenum-Palladium .mu.-Alkylidene Complexes. X-ray Structure of [PdI[.mu.-C(p-tolyl)dmba][.mu.-CO]Mo(Cp)(CN-t-Bu)2]

Organometallics ◽

10.1021/om00004a018 ◽

1995 ◽

Vol 14 (4) ◽

pp. 1637-1645 ◽

Cited By ~ 14

Author(s):

Alceo Macchioni ◽

Paul S. Pregosin ◽

Philippus F. Engel ◽

Stefan Mecking ◽

Michel Pfeffer ◽

...

Keyword(s):

Nmr Studies ◽

X Ray ◽

Multinuclear Nmr ◽

Tert Butyl ◽

Alkylidene Complexes

ChemInform Abstract: Synthesis and Structure of Group 5 Metal Alkyl and Alkylidene Complexes Containing 2,6-Dialkylphenoxide Ligands: X-Ray Crystal Structures of (Ta(OC6H3Me2-2,6)2(CH2Ph)3), (Ta(OC6H3Me2-2,6)4Me), and (Ta(OC6H3tBu2-2,6)2(=CHSiMe3)(CH2SiMe

ChemInform ◽

10.1002/chin.198723232 ◽

1987 ◽

Vol 18 (23) ◽

Author(s):

L. R. CHAMBERLAIN ◽

I. P. ROTHWELL ◽

K. FOLTING ◽

J. C. HUFFMAN

Keyword(s):

Crystal Structures ◽

X Ray ◽

Group 5 ◽

Alkylidene Complexes

ChemInform Abstract: Multiple Metal-Carbon Bonds. Part 9. Preparation and Characterization of Several Alkylidene Complexes, M(η5-C5H5)2(alkylidene)X (M = Ta or Nb), and the X-Ray Structure of Ta(η5-C5H5)2(CHC6H5)(CH2C6H5). An Investigation of Alkylidene L

Chemischer Informationsdienst ◽

10.1002/chin.197837287 ◽

1978 ◽

Vol 9 (37) ◽

Author(s):

R. R. SCHROCK ◽

L. W. MESSERLE ◽

C. D. WOOD ◽

L. J. GUGGENBERGER

Keyword(s):

X Ray ◽

Carbon Bonds ◽

Alkylidene Complexes

Alkyne polymerizations initiated by µ-alkylidene complexes of tungsten. X-Ray crystal structure of a chain-carrier intermediate

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39810001055 ◽

1981 ◽

pp. 1055-1057 ◽

Cited By ~ 12

Author(s):

Jacques Levisalles ◽

Francoise Rose-Munch ◽

Henri Rudler ◽

Jean-Claude Daran ◽

Yves Dromzee ◽

...

Keyword(s):

Crystal Structure ◽

X Ray ◽

A Chain ◽

Alkylidene Complexes

Synthesis and Reactivity of Tantalum Alkylidene Complexes Containing theC,N,N‘-Chelating Aryldiamine Ligand [C6H4(CH2N(Me)CH2CH2NMe2)-2]-(CNN). X-ray Structures of [TaCl2(CH-t-Bu)(CNN)], [Ta{(CH2)3-1,3}(CNN)(O-t-Bu)2], and [Ta(CNN)(O-t-Bu)2(H2CCH2)]

Organometallics ◽

10.1021/om9606799 ◽

1997 ◽

Vol 16 (8) ◽

pp. 1674-1684 ◽

Cited By ~ 25

Author(s):

Marco H. P. Rietveld ◽

Wendy Teunissen ◽

Henk Hagen ◽

Leon van de Water ◽

David M. Grove ◽

...

Keyword(s):

X Ray ◽

Alkylidene Complexes

Multiple metal-carbon bonds. 9. Preparation and characterization of several alkylidene complexes, M(.eta.5-C5H5)2(alkylidene)X (M = tantalum or niobium), and the x-ray structure of Ta(.eta.5-C5H5)2(CHC6H5)(CH2C6H5). An investigation of alkylidene ligand rotation

Journal of the American Chemical Society ◽

10.1021/ja00480a024 ◽

1978 ◽

Vol 100 (12) ◽

pp. 3793-3800 ◽

Cited By ~ 63

Author(s):

Richard R. Schrock ◽

Louis W. Messerle ◽

Clayton D. Wood ◽

Lloyd J. Guggenberger

Keyword(s):

X Ray ◽

Carbon Bonds ◽

Alkylidene Complexes

Synthesis of Hydride Tantalabenzocyclopentene and µ-Alkylidene Complexes by Direct Alkylation Reactions of [TaCpCp′Cl2] − NMR Spectroscopic Study and X-ray Crystal Structure of [TaCpCp′(H)(η2-CH2-CMe2-o-C6H4)], (Cp* = η5-C5Me5; Cp′ = η5-C5H4SiMe3)

European Journal of Inorganic Chemistry ◽

10.1002/1099-0682(200206)2002:6<1336::aid-ejic1336>3.0.co;2-r ◽

2002 ◽

Vol 2002 (6) ◽

pp. 1336-1342 ◽

Cited By ~ 10

Author(s):

Aurora Castro ◽

Mikhail V. Galakhov ◽

Manuel Gómez ◽

Pilar Gómez-Sal ◽

Avelino Martín

Keyword(s):

Crystal Structure ◽

Spectroscopic Study ◽

X Ray ◽

Alkylation Reactions ◽

Alkylidene Complexes

Thulium Alkylidene Complexes: Synthesis, X-ray Structures, and Reactivity

Formation and Selective Trapping of 2,5-Dihydropyridine and Its Isopropylidene Derivative by Tungsten(0) Alkylidene Complexes. X-ray Structure of the 5-Isopropylidene-2,5-dihydropyridine Adduct

The synthesis and structure of Group 5 metal alkyl and alkylidene complexes containing 2,6-dialkylphenoxide ligands: X-ray crystal structures of [Ta(OC6H3Me2-2,6)2(CH2Ph)3], [Ta(OC6H3Me2-2,6)4Me], and [Ta(OC6H3But2-2,6)2(CHSiMe3)(CH2SiMe3)]

Multinuclear NMR Studies and Reaction with tert-Butyl Isocyanide of Dinuclear Tungsten- or Molybdenum-Palladium .mu.-Alkylidene Complexes. X-ray Structure of [PdI[.mu.-C(p-tolyl)dmba][.mu.-CO]Mo(Cp)(CN-t-Bu)2]

ChemInform Abstract: Synthesis and Structure of Group 5 Metal Alkyl and Alkylidene Complexes Containing 2,6-Dialkylphenoxide Ligands: X-Ray Crystal Structures of (Ta(OC6H3Me2-2,6)2(CH2Ph)3), (Ta(OC6H3Me2-2,6)4Me), and (Ta(OC6H3tBu2-2,6)2(=CHSiMe3)(CH2SiMe

ChemInform Abstract: Multiple Metal-Carbon Bonds. Part 9. Preparation and Characterization of Several Alkylidene Complexes, M(η5-C5H5)2(alkylidene)X (M = Ta or Nb), and the X-Ray Structure of Ta(η5-C5H5)2(CHC6H5)(CH2C6H5). An Investigation of Alkylidene L

Alkyne polymerizations initiated by µ-alkylidene complexes of tungsten. X-Ray crystal structure of a chain-carrier intermediate

Synthesis and Reactivity of Tantalum Alkylidene Complexes Containing theC,N,N‘-Chelating Aryldiamine Ligand [C6H4(CH2N(Me)CH2CH2NMe2)-2]-(CNN). X-ray Structures of [TaCl2(CH-t-Bu)(CNN)], [Ta{(CH2)3-1,3}(CNN)(O-t-Bu)2], and [Ta(CNN)(O-t-Bu)2(H2CCH2)]

Multiple metal-carbon bonds. 9. Preparation and characterization of several alkylidene complexes, M(.eta.5-C5H5)2(alkylidene)X (M = tantalum or niobium), and the x-ray structure of Ta(.eta.5-C5H5)2(CHC6H5)(CH2C6H5). An investigation of alkylidene ligand rotation

Synthesis of Hydride Tantalabenzocyclopentene and µ-Alkylidene Complexes by Direct Alkylation Reactions of [TaCp*Cp′Cl2] − NMR Spectroscopic Study and X-ray Crystal Structure of [TaCp*Cp′(H)(η2-CH2-CMe2-o-C6H4)], (Cp* = η5-C5Me5; Cp′ = η5-C5H4SiMe3)

Synthesis of Hydride Tantalabenzocyclopentene and µ-Alkylidene Complexes by Direct Alkylation Reactions of [TaCpCp′Cl2] − NMR Spectroscopic Study and X-ray Crystal Structure of [TaCpCp′(H)(η2-CH2-CMe2-o-C6H4)], (Cp* = η5-C5Me5; Cp′ = η5-C5H4SiMe3)