Palladium Complexes Bearing Novel Strongly Bent Trans-Spanning Diphosphine Ligands:  Synthesis, Characterization, and Catalytic Activity

2006 ◽  
Vol 25 (2) ◽  
pp. 375-381 ◽  
Author(s):  
Olga Grossman ◽  
Clarit Azerraf ◽  
Dmitri Gelman
Keyword(s):  
Catalytic Activity ◽  
Palladium Complexes ◽  
Diphosphine Ligands

Palladium Complexes with Metallocene-Bridged Bidentate Diphosphine Ligands:  Synthesis, Structure, and Catalytic Activity in Amination and Cross-Coupling Reactions

2006 ◽  
Vol 25 (11) ◽  
pp. 2750-2760 ◽  
Author(s):  
Oleg V. Gusev ◽  
Tat'yana A. Peganova ◽  
Alexander M. Kalsin ◽  
Nikolai V. Vologdin ◽  
Pavel V. Petrovskii ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Cross Coupling ◽  
Palladium Complexes ◽  
Diphosphine Ligands ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

Synthesis of heteroleptic phosphine–copper(i) complexes: fluorescence sensing and catalytic properties

2021 ◽  
Author(s):  
Chen-Lin Luo ◽  
Chu-Xing Hu ◽  
Ping Shang ◽  
Guan-Zhao Wen ◽  
Jia-Jun Zhu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Catalytic Properties ◽  
Silver Ions ◽  
High Catalytic Activity ◽  
Diphosphine Ligands ◽  
Fluorescence Sensing ◽  
Cuaac Reaction

A series of heteroleptic Cu(i) complexes were precisely synthesized using different bipyridine and diphosphine ligands. These complexes exhibited fluorescence sensing towards silver ions and high catalytic activity towards the CuAAC reaction.

Catalytic activity of chelating N-heterocyclic carbene palladium complexes towards selective phosphorylation of coumarins

2016 ◽  
Vol 818 ◽  
pp. 179-184 ◽  
Author(s):  
Liangru Yang ◽  
Xinchi Zhang ◽  
Jinwei Yuan ◽  
Yongmei Xiao ◽  
Pu Mao
Keyword(s):  
Catalytic Activity ◽  
Palladium Complexes

Homogeneous versus Supported ONN Pincer-Type Gold and Palladium Complexes: Catalytic Activity

ChemSusChem ◽  
2009 ◽  
Vol 2 (7) ◽  
pp. 650-657 ◽  
Author(s):  
Carolina del Pozo ◽  
Nathalie Debono ◽  
Avelino Corma ◽  
Marta Iglesias ◽  
Félix Sánchez
Keyword(s):  
Catalytic Activity ◽  
Palladium Complexes

Synthesis of sterically hindered N -benzyladamantyl substituted benzimidazol-2-ylidene palladium complexes and investigation of their catalytic activity in aqueous medium

Tetrahedron ◽  
2017 ◽  
Vol 73 (40) ◽  
pp. 5940-5945 ◽  
Author(s):  
Zineb Imene Dehimat ◽  
Aziz Paşahan ◽  
Dahmane Tebbani ◽  
Sedat Yaşar ◽  
İsmail Özdemir
Keyword(s):  
Catalytic Activity ◽  
Aqueous Medium ◽  
Palladium Complexes ◽  
Sterically Hindered

scholarly journals Amine-Catalysed Suzuki–Miyaura-Type Coupling? the Identification and Isolation of the Palladium Culprits.

2021 ◽  
Author(s):  
Mickaël Avanthay ◽  
Robin Bedford ◽  
Callum Begg ◽  
Dietrich Böse ◽  
Jonathan Clayden ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Cross Coupling ◽  
Boronic Acids ◽  
Palladium Complexes ◽  
Aryl Halides ◽  
Type Coupling ◽  
Paradigm Shifting

A recent report in Nature Catalysis detailed the potentially paradigm-shifting organocatalysis of Suzuki cross-coupling of aryl halides with aryl boronic acids, catalysed by simple amine species. We have conducted a reinvestigation of key claims in this paper across multiple academic and industrial laboratories that shows that the observed catalytic activity cannot be due to the amine, but rather is due to tricyclohexylphosphine palladium complexes that are readily entrained during the purification of the amine<b>.</b>

scholarly journals Polystyrene-Supported Acyclic Diaminocarbene Palladium Complexes in Sonogashira Cross-Coupling: Stability vs. Catalytic Activity

Catalysts ◽  
2018 ◽  
Vol 8 (4) ◽  
pp. 141 ◽  
Author(s):  
Vladimir Mikhaylov ◽  
Viktor Sorokoumov ◽  
Denis Liakhov ◽  
Alexander Tskhovrebov ◽  
Irina Balova
Keyword(s):  
Catalytic Activity ◽  
High Activity ◽  
Cross Coupling ◽  
Palladium Complexes ◽  
Lower Activity ◽  
Coupling Conditions ◽  
Acyclic Diaminocarbene ◽  
Supported Palladium ◽  
Polymer Supported

Two types of immobilized on the amino-functionalized polystyrene-supported acyclic diaminocarbene palladium complexes (ADC-PdII) are investigated under Sonogashira cross-coupling conditions. Depending on substituents in the diaminocarbene fragment immobilized ADC-PdII, systems are found to have different catalytic activity and stability regarding Pd-leaching. PdII-diaminocarbenes possessing protons at both nitrogen atoms smoothly decompose into Pd0-containing species providing a catalytic “cocktail system” with high activity and ability to reuse within nine runs. Polymer-supported palladium (II) complex bearing NBn–Ccarbene–NH-moiety exhibits greater stability while noticeably lower activity under Sonogashira cross-coupling. Four molecular ADC-PdII complexes are also synthesized and investigated with the aim of confirming proposed base-promoted pathway of ADC-PdII conversion through carbodiimide into an active Pd0 forms.

scholarly journals Preparation of monocarbonyl ruthenium complexes bearing bidentate nitrogen and phosphine ligands and their catalytic activity in carbonyl compound reduction

2019 ◽  
Vol 48 (33) ◽  
pp. 12560-12576 ◽  
Author(s):  
Steven Giboulot ◽  
Clara Comuzzi ◽  
Alessandro Del Zotto ◽  
Rosario Figliolia ◽  
Giovanna Lippe ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Carbonyl Compound ◽  
Ruthenium Complexes ◽  
Ruthenium Catalysts ◽  
Phosphine Ligands ◽  
Diphosphine Ligands ◽  
Straightforward Approach

A series of novel monocarbonyl ruthenium catalysts containing bidentate dinitrogen or/and diphosphine ligands are easily obtained through a general and straightforward approach.

Increased Catalytic Activity of Surface-Immobilized Palladium Complexes in the Fluorogenic Deprotection of an Alloc-Derivatized Coumarin

2011 ◽  
Vol 18 (3) ◽  
pp. 788-792 ◽  
Author(s):  
Antony Fernandes ◽  
Peter Hensenne ◽  
Bertrand Mathy ◽  
Weiming Guo ◽  
Bernard Nysten ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Palladium Complexes
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