Modeling the Chemical Conversion of Organic Compounds in Sodium Borohydride Reduction Reactions

2008 ◽  
Vol 12 (3) ◽  
pp. 456-463 ◽  
Author(s):  
Ruth M. Tinnacher ◽  
Bruce D. Honeyman
Keyword(s):  
Organic Compounds ◽  
Sodium Borohydride ◽  
Chemical Conversion ◽  
Borohydride Reduction ◽  
Reduction Reactions ◽  
Sodium Borohydride Reduction

Electrochemical Synthesis of Deuterio Organic Compounds. I. Electrochemical Reduction of 1-Halonaphthalenes and Synthesis of 1-Chloro-4-methylnaphthalene

1974 ◽  
Vol 52 (3) ◽  
pp. 376-380 ◽  
Author(s):  
Roger N. Renaud
Keyword(s):  
Electrochemical Reduction ◽  
Organic Compounds ◽  
Sodium Borohydride ◽  
Deuterium Content ◽  
Borohydride Reduction ◽  
Deuterated Water ◽  
Chloro Derivative ◽  
Simultaneous Transfer ◽  
Sodium Borohydride Reduction ◽  
Methyl Naphthalene

Electrochemical reduction of 1-chloro-, 1-bromo-, 1-iodo-, 1-chloro-4-methyl-, and 1-bromo-4-methyl naphthalene was done in presence of deuterated water. The deuterium content of the naphthalene obtained reveals that the mechanism for the bromo and the iodo derivatives might involve either a simultaneous transfer of two electrons or an organometallic intermediate, while reduction of the chloro derivative might proceed at least partially via a radical intermediate.The synthesis of 1-chloro-4-methylnaphthalene from 1-chloro-4-chloromethylnaphthalene was achieved either by selective sodium borohydride reduction or by selective electrochemical reduction.

scholarly journals FACILE PREPARATION OF PLATINUM SOLS BY SODIUM BOROHYDRIDE REDUCTION AND ITS EVALUATION IN THE PHOTOSENSITIZED REDUCTION OF WATER TO HYDROGEN

1983 ◽  
Vol 12 (6) ◽  
pp. 893-896 ◽  
Author(s):  
Yohmei Okuno ◽  
Yukihiro Chiba ◽  
Osamu Yonemitsu
Keyword(s):  
Sodium Borohydride ◽  
Borohydride Reduction ◽  
Sodium Borohydride Reduction ◽  
Facile Preparation

1,2-Benzothiazines. II. The Preparation and Sodium Borohydride Reduction of 3-Acyl-2H-1,2-benzothiazin-4(3H)-one 1,1-Dioxides1

1965 ◽  
Vol 30 (7) ◽  
pp. 2241-2246 ◽  
Author(s):  
Harold Zinnes ◽  
Roger A. Comes ◽  
Francis R. Zuleski ◽  
Albert N. Caro ◽  
John Shavel
Keyword(s):  
Sodium Borohydride ◽  
Borohydride Reduction ◽  
Sodium Borohydride Reduction

ChemInform Abstract: Cobalt(II) Chloride-Catalyzed Chemoselective Sodium Borohydride Reduction of Azides in Water.

ChemInform ◽  
2010 ◽  
Vol 31 (36) ◽  
pp. no-no
Author(s):  
Francesco Fringuelli ◽  
Ferdinando Pizzo ◽  
Luigi Vaccaro
Keyword(s):  
Sodium Borohydride ◽  
Borohydride Reduction ◽  
Sodium Borohydride Reduction
Sign in / Sign up

Export Citation Format

Share Document