scholarly journals Toward a Stochastic Relaxation for the Quasi‐Equilibrium Theory of Cumulus Parameterization: Multicloud Instability, Multiple Equilibria, and Chaotic Dynamics

2019 ◽  
Vol 11 (8) ◽  
pp. 2474-2502
Author(s):  
Boualem Khouider ◽  
Etienne Leclerc
Keyword(s):  
Chaotic Dynamics ◽  
Multiple Equilibria ◽  
Equilibrium Theory ◽  
Cumulus Parameterization ◽  
Quasi Equilibrium ◽  
Stochastic Relaxation

Improved Rate Expression in the Quasi‐Equilibrium Theory of Mass Spectra

1962 ◽  
Vol 37 (6) ◽  
pp. 1276-1283 ◽  
Author(s):  
Marvin Vestal ◽  
Austin L. Wahrhaftig ◽  
William H. Johnston
Keyword(s):  
Mass Spectra ◽  
Equilibrium Theory ◽  
Quasi Equilibrium ◽  
Rate Expression

The isolation of 11-oxotetrahydrorhombifoline from Ormosia coutinhoi and a study of its mass spectrum

1967 ◽  
Vol 45 (7) ◽  
pp. 751-757 ◽  
Author(s):  
Stewart McLean ◽  
A. G. Harrison ◽  
D. G. Murray
Keyword(s):  
Mass Spectrum ◽  
Electron Impact ◽  
Mass Spectra ◽  
Equilibrium Theory ◽  
Side Chain ◽  
Fragmentation Reaction ◽  
Quasi Equilibrium ◽  
Molecular Ion ◽  
Dihydro Derivative ◽  
A Minor

11-Oxotetrahydrorhombifoline (I) has been isolated from the alkaloidal extract of the bark of Ormosia coutinhoi, and its dihydro derivative II has been prepared. An examination of the mass spectra of these compounds and of their 3,3-d2 derivatives has led to the elucidation of the course of the major electron impact induced fragmentations undergone by the molecules. The main fragmentation of I leads to loss of C3H5 from the side chain to form an ion of m/e 221, with a minor path involving a central fission of the molecular ion to form an ion of m/e 150. The mass spectrum of II shows that the loss of C3H7 to form the ion of m/e 221 is a minor process, the main fragmentation reaction involving a central fission to form an ion of m/e 152 analogous to the ion of m/e 150 from I. This change in the spectrum is shown to be consistent with predictions based on the quasi-equilibrium theory of mass spectra.

Substituent effects in unimolecular ion decompositions. XV. Mechanistic interpretations and the quasi-equilibrium theory

1970 ◽  
Vol 92 (23) ◽  
pp. 6867-6880 ◽  
Author(s):  
Fred W. McLafferty ◽  
Timothy. Wachs ◽  
Chava. Lifshitz ◽  
Giuseppe. Innorta ◽  
Philip. Irving
Keyword(s):  
Substituent Effects ◽  
Equilibrium Theory ◽  
Quasi Equilibrium

Quasi-Equilibrium Theory (QET)

2016 ◽  
Author(s):  
Kermit K. Murray ◽  
Robert K. Boyd ◽  
Marcos N. Eberlin ◽  
G. John Langley ◽  
Liang Li ◽  
...  
Keyword(s):  
Equilibrium Theory ◽  
Quasi Equilibrium
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