Coordination chemistry

We report the synthesis of two isomeric Pt(II) complexes ligated by doubly deprotonated 1,1′-bis(<i>o</i>-carborane) (<b>bc</b>). This work provides a potential route to fine-tune the electronic properties of luminescent metal complexes by virtue of vertex-differentiated coordination chemistry of carborane-based ligands.

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Aspects of the coordination chemistry of oxorhenium(V) and oxorhenium(VII) complexes

10.31274/rtd-180813-13610 ◽

2000 ◽

Author(s):

David William Lahti

Keyword(s):

Coordination Chemistry

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Faculty Opinions recommendation of Imperfect coordination chemistry facilitates metal ion release in the Psa permease.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.718170860.793499535 ◽

2014 ◽

Author(s):

Ian Roberts ◽

Helen Jesse

Keyword(s):

Coordination Chemistry ◽

Metal Ion ◽

Ion Release ◽

Metal Ion Release

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J. E. FALK, Porphyrins and Metalloporphyrins. Their General, Physical and Coordination Chemistry and Laboratory Methods. 1. Aufl. 266 S., 21 Abb., 36 Tab. Amsterdam 1964: Elsevier Publ. Comp. DM 42.—

Zeitschrift für allgemeine Mikrobiologie ◽

10.1002/jobm.3630040512 ◽

1964 ◽

Vol 4 (5) ◽

pp. 398-398

Author(s):

H. Berg

Keyword(s):

Coordination Chemistry ◽

Laboratory Methods ◽

General Physical

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The Coordination Chemistry of Phosphoryl Compounds Containing the — N(CH3)2 Group, Part VIII

Zeitschrift für Naturforschung B ◽

10.1515/znb-1972-0706 ◽

1972 ◽

Vol 27 (7) ◽

pp. 759-763 ◽

Cited By ~ 11

Author(s):

M. W. G. De Bolster ◽

W. L. Groeneveld

Keyword(s):

Coordination Chemistry ◽

General Formula ◽

Ligand Field ◽

Chemical Analyses ◽

X Ray ◽

Physical Measurements ◽

Ligand Field Spectra ◽

Chloride Adduct ◽

Ligand Field Parameters ◽

Group Part

A number of new solvates and adducts containing bisphenyldimethylaminophosphine oxide is reported. The solvates have the general formula M[(C6H5)2P(O)N(CH3)2]42+(anion-)2, in which M = Mg, Ca, Mn, Fe, Co, Ni, Cu, Zn and Cd, and the anions are ClO4- and BF4-. The adducts have the general formula M[(C6H5)2P(O)N(CH3)2]2Cl2, where M stands for the same series of metals.The compounds are characterized and identified by chemical analyses and physical measurements.Ligand-field and vibrational spectra have been investigated; values for the ligand-field parameters are reported. It is concluded that coordination takes place via the oxygen atom of the ligand.X-ray powder patterns were used in combination with ligand-field spectra to deduce the coordination around the metal ions.The interesting behaviour of the nickel (II) chloride adduct upon heating is discussed and it is shown that both a square pyramidal and a tetrahedral modification exists.

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