Stabilised phosphorus(i) and arsenic(i) iodide: readily-synthesised reagents for low oxidation state main group chemistryElectronic supplementary information (ESI) available: summary of DFT calculation and crystallographic data. See http://www.rsc.org/suppdata/cc/b3/b302292g/

2003 ◽  
pp. 1946 ◽  
Author(s):  
Bobby D. Ellis ◽  
Michelle Carlesimo ◽  
Charles L. B. Macdonald
Keyword(s):  
Oxidation State ◽  
Dft Calculation ◽  
Main Group ◽  
Crystallographic Data ◽  
Supplementary Information ◽  
Low Oxidation State

Donor–acceptor chemistry in the main group

2014 ◽  
Vol 43 (23) ◽  
pp. 8577-8586 ◽  
Author(s):  
Eric Rivard
Keyword(s):  
Oxidation State ◽  
Main Group ◽  
Donor Acceptor ◽  
Low Oxidation State

This Perspective article describes the preparation of low-oxidation state main group hydrides using a general donor–acceptor strategy.

Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin

2011 ◽  
Vol 47 (24) ◽  
pp. 6987 ◽  
Author(s):  
S. M. Ibrahim Al-Rafia ◽  
Adam C. Malcolm ◽  
Sean K. Liew ◽  
Michael J. Ferguson ◽  
Robert McDonald ◽  
...  
Keyword(s):  
Oxidation State ◽  
Main Group ◽  
Low Oxidation State

Kinetic stabilization of low-oxidation state and terminal hydrido main group metal complexes by a sterically demanding N,N′-bis(2,6-terphenyl)triazenide

2019 ◽  
Vol 48 (35) ◽  
pp. 13197-13204 ◽  
Author(s):  
Anthony R. Leverett ◽  
Vera Diachenko ◽  
Marcus L. Cole ◽  
Alasdair I. McKay
Keyword(s):  
Metal Complexes ◽  
Oxidation State ◽  
Main Group ◽  
Group Metal ◽  
Main Group Metal ◽  
Sterically Demanding ◽  
Low Oxidation State ◽  
Hydride Ligands

Thermally robust main group metal complexes featuring terminal hydride ligands are achieved by deploying a sterically demanding N,N′-bis(2,6-terphenyl)triazenide ligand.

Low Oxidation State Main Group

2006 ◽  
Author(s):  
Charles L. B. Macdonald ◽  
Bobby D. Ellis
Keyword(s):  
Oxidation State ◽  
Main Group ◽  
Low Oxidation State
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