Extremely bulky amido-group 14 element chloride complexes: Potential synthons for low oxidation state main group chemistry

2011 ◽  
Vol 40 (40) ◽  
pp. 10448 ◽  
Author(s):  
Jiaye Li ◽  
Andreas Stasch ◽  
Christian Schenk ◽  
Cameron Jones
Keyword(s):  
Oxidation State ◽  
Main Group ◽  
Group 14 ◽  
Chloride Complexes ◽  
Amido Group ◽  
Main Group Chemistry ◽  
Low Oxidation State

Utilisation of a lithium boryl as a reducing agent in low oxidation state group 15 chemistry: synthesis and characterisation of an amido-distibene and a boryl-dibismuthene

2015 ◽  
Vol 51 (33) ◽  
pp. 7128-7131 ◽  
Author(s):  
Deepak Dange ◽  
Amelia Davey ◽  
Joseph A. B. Abdalla ◽  
Simon Aldridge ◽  
Cameron Jones
Keyword(s):  
Oxidation State ◽  
Reducing Agent ◽  
Amido Group ◽  
Group 15 ◽  
Low Oxidation State ◽  
State Group

The first examples of an amido-distibene and a boryl dibismuthene (see picture) have been prepared by reaction of a lithium boryl complex with extremely bulky amido-group 15 dihalide precursor compounds.

Donor–acceptor chemistry in the main group

2014 ◽  
Vol 43 (23) ◽  
pp. 8577-8586 ◽  
Author(s):  
Eric Rivard
Keyword(s):  
Oxidation State ◽  
Main Group ◽  
Donor Acceptor ◽  
Low Oxidation State

This Perspective article describes the preparation of low-oxidation state main group hydrides using a general donor–acceptor strategy.

Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin

2011 ◽  
Vol 47 (24) ◽  
pp. 6987 ◽  
Author(s):  
S. M. Ibrahim Al-Rafia ◽  
Adam C. Malcolm ◽  
Sean K. Liew ◽  
Michael J. Ferguson ◽  
Robert McDonald ◽  
...  
Keyword(s):  
Oxidation State ◽  
Main Group ◽  
Low Oxidation State

Kinetic stabilization of low-oxidation state and terminal hydrido main group metal complexes by a sterically demanding N,N′-bis(2,6-terphenyl)triazenide

2019 ◽  
Vol 48 (35) ◽  
pp. 13197-13204 ◽  
Author(s):  
Anthony R. Leverett ◽  
Vera Diachenko ◽  
Marcus L. Cole ◽  
Alasdair I. McKay
Keyword(s):  
Metal Complexes ◽  
Oxidation State ◽  
Main Group ◽  
Group Metal ◽  
Main Group Metal ◽  
Sterically Demanding ◽  
Low Oxidation State ◽  
Hydride Ligands

Thermally robust main group metal complexes featuring terminal hydride ligands are achieved by deploying a sterically demanding N,N′-bis(2,6-terphenyl)triazenide ligand.

Transition metal-mediated donor–acceptor coordination of low-oxidation state Group 14 element halides

2016 ◽  
Vol 45 (14) ◽  
pp. 6071-6078 ◽  
Author(s):  
Anindya K. Swarnakar ◽  
Michael J. Ferguson ◽  
Robert McDonald ◽  
Eric Rivard
Keyword(s):  
Transition Metal ◽  
Oxidation State ◽  
Bond Activation ◽  
Main Group ◽  
Group Element ◽  
Group 14 ◽  
Acidic Group ◽  
Main Group Element ◽  
Donor Acceptor ◽  
State Group

The main group element triggered C–H bond activation of a Rh-bound Cp ligand is reported. The key aspect of this transformation is the presence of a highly Lewis acidic Group 14 element site.

Low Oxidation State Main Group

2006 ◽  
Author(s):  
Charles L. B. Macdonald ◽  
Bobby D. Ellis
Keyword(s):  
Oxidation State ◽  
Main Group ◽  
Low Oxidation State
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