Kinetic stabilization of low-oxidation state and terminal hydrido main group metal complexes by a sterically demanding N,N′-bis(2,6-terphenyl)triazenide

2019 ◽  
Vol 48 (35) ◽  
pp. 13197-13204 ◽  
Author(s):  
Anthony R. Leverett ◽  
Vera Diachenko ◽  
Marcus L. Cole ◽  
Alasdair I. McKay
Keyword(s):  
Metal Complexes ◽  
Oxidation State ◽  
Main Group ◽  
Group Metal ◽  
Main Group Metal ◽  
Sterically Demanding ◽  
Low Oxidation State ◽  
Hydride Ligands

Thermally robust main group metal complexes featuring terminal hydride ligands are achieved by deploying a sterically demanding N,N′-bis(2,6-terphenyl)triazenide ligand.

Reversible Addition of Carbon Dioxide to Main Group Metal Complexes at Temperatures about 0 °C

2021 ◽  
Author(s):  
Tatyana S. Koptseva ◽  
Vladimir G. Sokolov ◽  
Sergey Yu. Ketkov ◽  
Elena A. Rychagova ◽  
Anton V. Cherkasov ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Complexes ◽  
Main Group ◽  
Group Metal ◽  
Reversible Addition ◽  
Main Group Metal

Main-group metal complexes of α-diimine ligands: structure, bonding and reactivity

2021 ◽  
Author(s):  
Rong Zhang ◽  
Yanchao Wang ◽  
Yanxia Zhao ◽  
Carl Redshaw ◽  
Igor L. Fedushkin ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Small Molecule ◽  
Main Group ◽  
Group Metal ◽  
Diimine Ligands ◽  
Main Group Metal ◽  
Metal Metal ◽  
Low Valent

The use of dad (and bian) ligands in the stabilization of main-group complexes, in particular metal–metal-bonded compounds, as well as the small molecule reactivity of these (low-valent) metal complexes, is summarized.

Novel isomorphism of two hexagonal non-centrosymmetric hybrid crystals of M(en)3Ag2I4 (M = transition metal Mn2+ or main-group metal Mg2+; en = ethylenediamine)

CrystEngComm ◽  
2018 ◽  
Vol 20 (3) ◽  
pp. 356-361 ◽  
Author(s):  
Xin Chen ◽  
Zhi-Yuan Yao ◽  
Chen Xue ◽  
Zhu-Xi Yang ◽  
Jian-Lan Liu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Main Group ◽  
Group Metal ◽  
Main Group Metal ◽  
Hybrid Crystals ◽  
First Time

For the first time, a main-group metal complex is used as a template for the formation of hybrid crystal structures and isomorphic hybrid crystals are obtained using transition and main-group metal complexes.

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