Thermal solid state synthesis of coordination complexes from hydrogen bonded precursors

2005 ◽  
pp. 2457 ◽  
Author(s):  
Christopher J. Adams ◽  
Paul C. Crawford ◽  
A. Guy Orpen ◽  
Thomas J. Podesta ◽  
Benjamin Salt
Keyword(s):  
Solid State ◽  
Coordination Complexes ◽  
Solid State Synthesis ◽  
Hydrogen Bonded

A Step Towards a [2.2]Paracyclophane: A Single Crystal to Single Crystal Reaction Involving a Hydrogen-Bonded Molecular Assembly with Multiple Reaction Centres

2006 ◽  
Vol 59 (9) ◽  
pp. 613 ◽  
Author(s):  
Tomislav Friščić ◽  
Leonard R. MacGillivray
Keyword(s):  
Solid State ◽  
Single Crystal ◽  
Absorption Edge ◽  
Molecular Assembly ◽  
Solid State Synthesis ◽  
State Transformation ◽  
Molecular Assemblies ◽  
Solid State Transformation ◽  
Reaction Centres ◽  
Hydrogen Bonded

A single crystal to single crystal [2+2] photodimerization has been achieved within a molecular cocrystal composed of finite, hydrogen-bonded molecular assemblies using the absorption-edge irradiation technique. The cocrystal is composed of a resorcinol template and a diolefin reactant that reacts to form a non-symmetrical cyclobutane product. The product is an intermediate in a two-step solid-state synthesis of a [2.2]paracyclophane. The ability to conduct the reaction in a single crystal to single crystal fashion attests to the robustness of the hydrogen-bonded assemblies during the course of the solid-state transformation.

Solid state synthesis of MZrO3 (M = Pb, Cd and Cu) photocatalyst-A Green chemistry approach

2011 ◽  
Vol 3 (7) ◽  
pp. 335-340
Author(s):  
Ashok Vishram Borhade ◽  
◽  
Vishwas Bhaskar Gaikwad ◽  
Yogeshwar Rajaram Baste
Keyword(s):  
Solid State ◽  
Green Chemistry ◽  
Solid State Synthesis

Solid-state synthesis and catalysis property of copper phthalocyanine

2014 ◽  
Author(s):  
Mingtian Li ◽  
Hong Wang ◽  
Lanying Yu ◽  
RuiSong Yang
Keyword(s):  
Solid State ◽  
Copper Phthalocyanine ◽  
Solid State Synthesis

Solid-state Synthesis and Properties of Copolymers of Aniline and o-Methoxyaniline

2012 ◽  
Vol 29 (10) ◽  
pp. 1117
Author(s):  
Abdiryim Tursun ◽  
Jamal Ruxangul ◽  
Awut Tunsagul ◽  
Nurulla Ismayil ◽  
Feng XU ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Synthesis

Solid-state synthesis and characterization of two-dimensional hexagonal BCN nanosheet using a free template method

2021 ◽  
Vol 115 ◽  
pp. 108350
Author(s):  
Majid Mirzaee ◽  
Alimorad Rashidi ◽  
Ashkan Zolriasatein ◽  
Majid Rezaei Abadchi
Keyword(s):  
Solid State ◽  
Solid State Synthesis ◽  
Synthesis And Characterization ◽  
Template Method ◽  
Two Dimensional

Solid-State Synthesis of Highly Dispersed Nitrogen-Coordinated Single Iron Atom Electrocatalysts for Proton Exchange Membrane Fuel Cells

Nano Letters ◽  
2021 ◽  
Author(s):  
Fei Xiao ◽  
Xiang Liu ◽  
Cheng-Jun Sun ◽  
Inhui Hwang ◽  
Qi Wang ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Solid State ◽  
Iron Atom ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Solid State Synthesis ◽  
Highly Dispersed ◽  
Exchange Membrane

Solid-State Synthesis and Photodegradation Property of Anatase TiO2 Micro-Nanopowder by Sodium Replacement

2021 ◽  
pp. 106589
Author(s):  
Liu Shao-you ◽  
Zuo Cheng-gang ◽  
Xia Jie
Keyword(s):  
Solid State ◽  
Anatase Tio2 ◽  
Solid State Synthesis ◽  
Sodium Replacement

Janus Pyrrolopyrrole aza‐Dipyrrin: Hydrogen‐Bonded Assemblies and Slow Magnetic Relaxation of the Cobalt(II) Complex in the Solid State

2021 ◽  
Author(s):  
Toshiharu Ishizaki ◽  
Hideaki Karasaki ◽  
Yuto Kage ◽  
Misaki Kamioka ◽  
Yitong Wang ◽  
...  
Keyword(s):  
Solid State ◽  
Magnetic Relaxation ◽  
Slow Magnetic Relaxation ◽  
Hydrogen Bonded

The origin of chemical inhomogeneity in lead-free potassium sodium niobate ceramic: Competitive chemical reaction during solid-state synthesis

2021 ◽  
Vol 211 ◽  
pp. 116833
Author(s):  
Hao-Cheng Thong ◽  
Alexis Payne ◽  
Jia-Wang Li ◽  
Yue-Yu-Shan Cheng ◽  
Jacob L. Jones ◽  
...  
Keyword(s):  
Solid State ◽  
Chemical Reaction ◽  
Solid State Synthesis ◽  
Lead Free ◽  
Chemical Inhomogeneity ◽  
Sodium Niobate ◽  
Potassium Sodium Niobate ◽  
Potassium Sodium

scholarly journals Spectroscopic, X-ray Diffraction and Density Functional Theory Study of Intra- and Intermolecular Hydrogen Bonds in Ortho-(4-tolylsulfonamido)benzamides

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 926
Author(s):  
Malose J. Mphahlele ◽  
Eugene E. Onwu ◽  
Marole M. Maluleka
Keyword(s):  
Density Functional Theory ◽  
Solid State ◽  
Hydrogen Bonds ◽  
Density Functional ◽  
Tetrahedral Geometry ◽  
Hindered Rotation ◽  
Hydrogen Bond Acceptor ◽  
Functional Theory ◽  
Vis Spectroscopy ◽  
Hydrogen Bonded

The conformations of the title compounds were determined in solution (NMR and UV-Vis spectroscopy) and in the solid state (FT-IR and XRD), complemented with density functional theory (DFT) in the gas phase. The nonequivalence of the amide protons of these compounds due to the hindered rotation of the C(O)–NH2 single bond resulted in two distinct resonances of different chemical shift values in the aromatic region of their 1H-NMR spectra. Intramolecular hydrogen bonding interactions between the carbonyl oxygen and the sulfonamide hydrogen atom were observed in the solution phase and solid state. XRD confirmed the ability of the amide moiety of this class of compounds to function as a hydrogen bond acceptor to form a six-membered hydrogen bonded ring and a donor simultaneously to form intermolecular hydrogen bonded complexes of the type N–H···O=S. The distorted tetrahedral geometry of the sulfur atom resulted in a deviation of the sulfonamide moiety from co-planarity of the anthranilamide scaffold, and this geometry enabled oxygen atoms to form hydrogen bonds in higher dimensions.

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