Reactions of aromatic nitro-compounds with hydroxide and methoxide: structural investigations by nuclear magnetic resonance spectroscopy

1965 ◽  
pp. 256
Author(s):  
M. R. Crampton ◽  
V. Gold
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Magnetic Resonance Spectroscopy ◽  
Nuclear Magnetic Resonance Spectroscopy ◽  
Nitro Compounds ◽  
Resonance Spectroscopy ◽  
Structural Investigations ◽  
Aromatic Nitro Compounds ◽  
Aromatic Nitro ◽  
Nuclear Magnetic

Interaction between aliphatic and aromatic nitro compounds in basic media

1968 ◽  
Vol 46 (19) ◽  
pp. 3047-3054 ◽  
Author(s):  
C. A. Fyfe
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Magnetic Resonance Spectroscopy ◽  
Nuclear Magnetic Resonance Spectroscopy ◽  
Nitro Compounds ◽  
Resonance Spectroscopy ◽  
Evidence Based ◽  
Aliphatic Nitro Compounds ◽  
Sigma Complexes ◽  
Aromatic Nitro

The interaction between aromatic and aliphatic nitro compounds in basic media has been investigated. Evidence based mainly on nuclear magnetic resonance spectroscopy suggests that the brightly colored species formed are sigma complexes. The generality of the reaction is investigated and its relation to the Janovsky reaction discussed.

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