Synthesis and characterization of trans-M2(TiPB)2(O2C-CHCH-2-C4H3S)2 (M = Mo or W) and comments on the metal-to-ligand charge transfer bands in MM quadruply bonded complexes of the type trans-M2(TiPB)2L2, where TiPB = 2,4,6-triisopropylbenzoate and L = π-accepting carboxylate ligand

2011 ◽  
Vol 40 (40) ◽  
pp. 10658 ◽  
Author(s):  
Brian G. Alberding ◽  
Malcolm H. Chisholm ◽  
Benjamin J. Lear ◽  
Vesal Naseri ◽  
Carly R. Reed
Keyword(s):  
Charge Transfer ◽  
Carboxylate Ligand ◽  
Synthesis And Characterization ◽  
Ligand Charge Transfer ◽  
Bonded Complexes ◽  
Quadruply Bonded Complexes

scholarly journals Synthesis and Characterization of Chloridobis(dimethylglyoximato)4-(2-ferrocenylvinyl)pyridinecobalt(III): A New Heterobinuclear Cobaloxime

2016 ◽  
Vol 2016 ◽  
pp. 1-5 ◽  
Author(s):  
Sebastián Pizarro ◽  
Guillermo Saá ◽  
Francisco Gajardo ◽  
Alvaro Delgadillo
Keyword(s):  
Cyclic Voltammetry ◽  
Charge Transfer ◽  
Elemental Analysis ◽  
Synthesis And Characterization ◽  
Cyclic Voltammogram ◽  
H Nmr ◽  
Ligand Charge Transfer

The synthesis of a new heterobinuclear cobaloxime with 4-(2-ferrocenylvinyl)pyridine, fcvpy, is reported. The complex [CoCl(dmgH)2(fcvpy)], where dmgH2is dimethylglyoxime and dmgH is dimethylglyoximato, has been characterized by1H-NMR, UV-Vis, cyclic voltammetry, and elemental analysis. The cyclic voltammogram of this complex shows a fc/fc+reversible wave at +0.58 V versus Ag/AgCl, one irreversible wave,Epc= −0.54 V versus Ag/AgCl, assigned to the reduction of Co(III) to Co(II), and two quasireversible processes at −1.02 V and −1.10 V versus Ag/AgCl associated with the reduction of Co(II). The complex showed ferrocene-ligand charge transfer bands at 334 nm and 505 nm. TDDFT/B3LYP/6-31G(d) calculations support this assignation.

Synthesis and characterization of π-conjugated oligomers that contain metal-to-ligand charge transfer chromophores†

1999 ◽  
pp. 1749-1750 ◽  
Author(s):  
Kevin D. Ley ◽  
Yiting Li ◽  
Jodie V. Johnson ◽  
David H. Powell ◽  
Kirk S. Schanze
Keyword(s):  
Charge Transfer ◽  
Synthesis And Characterization ◽  
Conjugated Oligomers ◽  
Ligand Charge Transfer

Synthesis and Characterization of Monosubstituted TTF and Its Solvent Dependent Mono- and Dication Charge-Transfer Salts

2009 ◽  
Vol 9 (9) ◽  
pp. 3855-3858 ◽  
Author(s):  
Yu Wang ◽  
Shuxin Cui ◽  
Bo Li ◽  
Jingping Zhang ◽  
Yan Zhang
Keyword(s):  
Charge Transfer ◽  
Synthesis And Characterization ◽  
Charge Transfer Salts

Synthesis and Characterization of Charge-Transfer Complexes of Π-Acceptor TCNQ with Various Phenols

2007 ◽  
Vol 469 (1) ◽  
pp. 99-110 ◽  
Author(s):  
Neelu Chouhan ◽  
M. L. Kalra ◽  
Sudhish Kumar ◽  
Y. N. Singh ◽  
Suresh C. Ameta
Keyword(s):  
Charge Transfer ◽  
Synthesis And Characterization ◽  
Charge Transfer Complexes

Synthesis and characterization of charge transfer salts based on DT-TTF and M(dcdmp)2 complexes

2006 ◽  
Vol 142 (3-4) ◽  
pp. 349-354 ◽  
Author(s):  
D. Belo ◽  
E. B. Lopes ◽  
I. C. Santos ◽  
J. C. Dias ◽  
M. Figueira ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Synthesis And Characterization ◽  
Charge Transfer Salts
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