Two genuine supramolecular isomers with a unique type of structural difference and completely different porous properties have been synthesized and characterized.
Three Nd(iii)–ndc2− coordination polymers were constructed using ndc2− ligands with hybrid coordination modes to generate octahedral SBUs for 1 and rod-shaped SBUs for 2 and 3, respectively.
Controlled bottom-up synthesis of amorphous coordination polymers with tailored metal coordination is a research field in its infancy. In this study, synthesis control was achieved to selectively prepare one-dimensional (1D)...
Mn(III) complexes with the non-chiral ligands, (E)-N-(2-((2-aminobenzylidene)amino)-2-methylpropyl)-5-X-2-hydroxybenzamide (HLX, X = H, Cl, Br, and I), crystallise as chiral conglomerates containing amide oxygen-bridged one-dimensional coordination polymers that exhibit weak ferromagnetism. The...