Gradient copolymers of styrene–methyl acrylate and styrene–acrylic acid by organostibine-mediated controlled/living radical polymerization and their glass transition behaviors

2013 ◽  
Vol 4 (17) ◽  
pp. 4639 ◽  
Author(s):  
Jinping Zhang ◽  
Jun Li ◽  
Liyan Huang ◽  
Zhengping Liu
Keyword(s):  
Glass Transition ◽  
Acrylic Acid ◽  
Radical Polymerization ◽  
Methyl Acrylate ◽  
Living Radical Polymerization ◽  
Gradient Copolymers ◽  
Controlled Living Radical Polymerization

scholarly journals One-pot synthesis for gradient copolymers via concurrent tandem living radical polymerization: mild and selective transesterification of methyl acrylate through Al(acac)3 with common alcohols

RSC Advances ◽  
2021 ◽  
Vol 11 (42) ◽  
pp. 26049-26055
Author(s):  
Tam Thi-Thanh Huynh ◽  
Si Eun Kim ◽  
Soon Cheon Kim ◽  
Jin Chul Kim ◽  
Young Il Park ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Methyl Acrylate ◽  
Living Radical Polymerization ◽  
One Pot ◽  
Gradient Copolymers ◽  
One Pot Synthesis

The acrylate based gradient copolymers were successfully synthesized by concurrent tandem living radical polymerization using Al(acac)3 as cocatalyst with common alcohols.

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