Topotactic elimination of water across a C–C ligand bond in a dense 3-D metal–organic framework

2014 ◽  
Vol 50 (87) ◽  
pp. 13292-13295 ◽  
Author(s):  
Hamish H.-M. Yeung ◽  
Monica Kosa ◽  
John M. Griffin ◽  
Clare P. Grey ◽  
Dan T. Major ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Metal Organic Framework ◽  
Structural Flexibility ◽  
Metal Organic ◽  
Ligand Bond ◽  
Organic Framework

Owing to its thermal stability and structural flexibility, the original 3-D framework of lithium l-malate remains intact upon topotactic dehydration.

Design of a MOF based on octa-nuclear zinc clusters realizing both thermal stability and structural flexibility

2022 ◽  
Author(s):  
Yunsheng Ma ◽  
Xiaoyan Tang ◽  
Ming Chen ◽  
Akio Mishima ◽  
Liangchun Li ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Dicarboxylic Acid ◽  
Metal Organic Framework ◽  
Structural Flexibility ◽  
Metal Organic ◽  
Zinc Clusters ◽  
Organic Framework

A octa-nuclear zinc (Zn8) cluster-based two-fold interpenetrated metal−organic framework (MOF) of [(CH3)2NH2]2[Zn8O3(FDC)6]·7DMF (denoted as Zn8-as; H2FDC = 9H-fluorene-2,7-dicarboxylic acid; DMF = N,N-dimethylformamide) was synthesized by reactions of a hard base...

Porous homo- and heterochiral cobalt(II) aspartates with high thermal stability of the metal-organic framework

2010 ◽  
Vol 59 (4) ◽  
pp. 733-740 ◽  
Author(s):  
M. P. Yutkin ◽  
M. S. Zavakhina ◽  
D. G. Samsonenko ◽  
D. N. Dybtsev ◽  
V. P. Fedin
Keyword(s):  
Thermal Stability ◽  
Metal Organic Framework ◽  
High Thermal Stability ◽  
Metal Organic ◽  
Thermal Stability Of ◽  
Organic Framework

A Novel (3,4,9)-Connected 3D Metal–Organic Framework Based on the Non-Planar Tricarboxyl Tecton and Zn5O4-Cluster SBU

2015 ◽  
Vol 68 (1) ◽  
pp. 161 ◽  
Author(s):  
Zhuo-Wei Wang ◽  
Hui Zhao ◽  
Min Chen ◽  
Min Hu
Keyword(s):  
Thermal Stability ◽  
Benzoic Acid ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Crystalline Material ◽  
Tripodal Ligand ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework

Combination of a non-planar tripodal ligand 3,4-bi(4-carboxyphenyl)-benzoic acid (H3L) and Zn5O4-cluster secondary building units affords a highly connected three-dimensional metal–organic framework, {[Zn5(μ3-OH)3(μ2-OH)L2(H2O)2](H2O)2}n (1), which exhibits an unusual (3,4,9)-connected (42.5)(3.43.52)(32.45.511.613.73.82) topological net. The thermal stability and solid luminescence of the crystalline material have also been investigated.

A lanthanide metal–organic framework with high thermal stability and available Lewis-acid metal sites

2006 ◽  
pp. 3172-3174 ◽  
Author(s):  
Xiaodan Guo ◽  
Guangshan Zhu ◽  
Zhongyue Li ◽  
Fuxing Sun ◽  
Zhenghong Yang ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Lewis Acid ◽  
Metal Organic Framework ◽  
High Thermal Stability ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Organic Framework

Synthesis, structure and photoluminescent behavior of a novel pillar-layered {Zn3}-based metal–organic framework

2016 ◽  
Vol 09 (01) ◽  
pp. 1650002 ◽  
Author(s):  
Xue-Zhi Song ◽  
Wen-Sheng Mu ◽  
Bing-Yan Han ◽  
Yang Yan
Keyword(s):  
Thermal Stability ◽  
Dicarboxylic Acid ◽  
Luminescent Property ◽  
Metal Organic Framework ◽  
Building Blocks ◽  
Metal Organic ◽  
Organic Framework

A novel 3D metal–organic framework (MOF) {[Zn3(bpdc)3 (p-4-bpmb)](DMF)2}n ( 1) (H[Formula: see text]-4,4′-dicarboxylic acid; p-4-[Formula: see text],4-bis(pyridine-4-ylmethoxy)benzene) has been solvothermally synthesized and structurally characterized. Compound 1 exhibits a 3D pillar-layered framework based on the trinuclear {Zn3} building blocks, consisting of Zn-dicarboxylate layers and bipyridyl-derivative pillars. Furthermore, it features three-fold interpenetrating 8-connected hex-type topology. In addition, its thermal stability and luminescent property have also been investigated.

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