Novel imidazolium and imidazolinium salts containing the 9-nickelafluorenyl anion – synthesis, structures and reactivity

2015 ◽  
Vol 44 (16) ◽  
pp. 7169-7176 ◽  
Author(s):  
Piotr Buchalski ◽  
Roman Pacholski ◽  
Krzysztof Chodkiewicz ◽  
Włodzimierz Buchowicz ◽  
Kinga Suwińska ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Carbene Complexes ◽  
Imidazolinium Salts

Investigation of the properties of carbene complexes is one of the most important fields of modern coordination chemistry.

Silicon(II) Coordination Chemistry: N-Heterocyclic Carbene Complexes of Si2+and SiI+

2013 ◽  
Vol 125 (27) ◽  
pp. 7112-7116 ◽  
Author(s):  
Alexander C. Filippou ◽  
Yury N. Lebedev ◽  
Oleg Chernov ◽  
Martin Straßmann ◽  
Gregor Schnakenburg
Keyword(s):  
Coordination Chemistry ◽  
Carbene Complexes

Calix[4]arenes with one and two N-linked imidazolium units as precursors of N-heterocyclic carbene complexes. Coordination chemistry and use in Suzuki–Miyaura cross-coupling

2011 ◽  
Vol 40 (38) ◽  
pp. 9889 ◽  
Author(s):  
Eric Brenner ◽  
Dominique Matt ◽  
Mickaël Henrion ◽  
Matthieu Teci ◽  
Loïc Toupet
Keyword(s):  
Coordination Chemistry ◽  
Cross Coupling ◽  
Carbene Complexes

Silicon(II) Coordination Chemistry: N-Heterocyclic Carbene Complexes of Si2+and SiI+

2013 ◽  
Vol 52 (27) ◽  
pp. 6974-6978 ◽  
Author(s):  
Alexander C. Filippou ◽  
Yury N. Lebedev ◽  
Oleg Chernov ◽  
Martin Straßmann ◽  
Gregor Schnakenburg
Keyword(s):  
Coordination Chemistry ◽  
Carbene Complexes

Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Carbene Complexes ◽  
New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands

2018 ◽  
Author(s):  
Kent O. Kirlikovali ◽  
Jonathan C. Axtell ◽  
Kierstyn Anderson ◽  
Peter I. Djurovich ◽  
Arnold L. Rheingold ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Fine Tuning ◽  
Fine Tune

We report the synthesis of two isomeric Pt(II) complexes ligated by doubly deprotonated 1,1′-bis(<i>o</i>-carborane) (<b>bc</b>). This work provides a potential route to fine-tune the electronic properties of luminescent metal complexes by virtue of vertex-differentiated coordination chemistry of carborane-based ligands.

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