Panchromatic co-sensitization of porphyrin-sensitized solar cells to harvest near-infrared light beyond 900 nm

2015 ◽  
Vol 3 (4) ◽  
pp. 1417-1420 ◽  
Author(s):  
Jia-Wei Shiu ◽  
Yen-Cheng Chang ◽  
Chien-Yi Chan ◽  
Hui-Ping Wu ◽  
Hung-Yu Hsu ◽  
...  

We designed a dimeric porphyrin dye based on an efficient push–pull zinc porphyrin with extended π-conjugation so that the light-harvesting ability exhibits a panchromatic feature covering a broad spectral region from 400 nm to 900 nm.

2014 ◽  
Vol 118 (30) ◽  
pp. 16618-16625 ◽  
Author(s):  
Takeshi Maeda ◽  
Shohei Nitta ◽  
Hidekazu Nakao ◽  
Shigeyuki Yagi ◽  
Hiroyuki Nakazumi

2018 ◽  
Vol 9 ◽  
pp. 2788-2793 ◽  
Author(s):  
Daiming Liu ◽  
Qingkang Wang ◽  
Qing Wang

The wastage of near-infrared light seriously restricts the photoelectric conversion efficiency of hydrogenated amorphous silicon (a-Si:H) thin film solar cells. Spectral upconversion is of great significance in reducing the wastage. Herein, the upconverting compound NaYF4:Yb3+/Er3+ was synthesized via a hydrothermal method. SEM and XRD results revealed the morphology and a phase transition from cubic to hexagonal NaYF4. Photoluminescence spectra indicated that the hexagonal NaYF4:Yb3+/Er3+ nanorods convert near-infrared light of 980 nm to the visible light with wavelength peaks at 654, 541 and 522 nm. Hence, the upconverting rods were incorporated in a polymethylmethacrylate (PMMA) layer on the rear side of a-Si:H solar cell. Under AM1.5 solar irradiation, a facile optical filter was used to scrutinize the effect of upconversion on the cell performance. Compared with a bare cell, the NaYF4:Yb3+/Er3+-based a-Si:H cell exhibited an 25% improved short-circuit current and an appreciable improvement of the near-infrared response of the external quantum efficiency. Moreover, because the size of the nanorods is comparable to the wavelength of visible light, the rods effectively scattered light, thus enhancing the visible light harvesting.


Nano Letters ◽  
2009 ◽  
Vol 9 (12) ◽  
pp. 4250-4257 ◽  
Author(s):  
Gopal K. Mor ◽  
Sanghoon Kim ◽  
Maggie Paulose ◽  
Oomman K. Varghese ◽  
Karthik Shankar ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (61) ◽  
pp. 38506-38511 ◽  
Author(s):  
Haiyong Guo ◽  
Zhen Hu ◽  
Li Zhao ◽  
Li Wan ◽  
Yadan Wu ◽  
...  

A new strategy to improve the efficiency of dye-sensitized solar cells by using the external near-infrared light harvesting and light-scattering dual-functional upconversion (UC) material NaLuF4:Yb3+/Er3+ is proposed.


2020 ◽  
Vol 217 (6) ◽  
pp. 1900921 ◽  
Author(s):  
Md. Mahabub Alam Moon ◽  
Md. Hasan Ali ◽  
Md. Ferdous Rahman ◽  
Jaker Hossain ◽  
Abu Bakar Md. Ismail

2020 ◽  
Vol 24 (10) ◽  
pp. 1189-1197
Author(s):  
Naresh Duvva ◽  
Suneel Gangada ◽  
Raghu Chitta ◽  
Lingamallu Giribabu

Limited synthetic steps via low-cost starting materials are needed to develop large-scale light-active materials for efficient solar cells. Here, novel bis(4[Formula: see text]-tert-butylbiphenyl-4-yl)aniline (BBA) based A3B zinc porphyrin (GB) is synthesized and applied as a light harvesting/electron injection material in dye-sensitized solar cells. The GB sensitizer was characterized by various spectroscopic techniques and the optimized device shows [Formula: see text] of 10.98 ± 0.37 mA/cm2 and power conversion efficiency (PCE) of 3.34 ± 0.26%. In addition, performance is enhanced up to ∼3.9% by the addition of co-adsorbent 3a,7a-dihydroxy-5b-cholic acid (chenodeoxycholic acid, CDCA) to minimize [Formula: see text]-[Formula: see text] staking of the planar porphyrin macrocycles. These results demonstrate that novel broad-absorbing light-active material (GB) could be used for indoor solar panels.


Sign in / Sign up

Export Citation Format

Share Document