scholarly journals Electrophilic trifluoromethylation of carbonyl compounds and their nitrogen derivatives under copper catalysis

2016 ◽  
Vol 52 (5) ◽  
pp. 869-881 ◽  
Author(s):  
Alexis Prieto ◽  
Olivier Baudoin ◽  
Didier Bouyssi ◽  
Nuno Monteiro

Recent advances in copper-catalyzed electrophilic trifluoromethylation of carbonyl compounds and their nitrogen derivatives are highlighted with particular focus on C–CF3 bond forming reactions.

2020 ◽  
Vol 23 (28) ◽  
pp. 3206-3225 ◽  
Author(s):  
Amol D. Sonawane ◽  
Mamoru Koketsu

: Over the last decades, many methods have been reported for the synthesis of selenium- heterocyclic scaffolds because of their interesting reactivities and applications in the medicinal as well as in the material chemistry. This review describes the recent numerous useful methodologies on C-Se bond formation reactions which were basically carried out at low and room temperature.


2016 ◽  
Vol 12 ◽  
pp. 444-461 ◽  
Author(s):  
Rajeev S Menon ◽  
Akkattu T Biju ◽  
Vijay Nair

N-Heterocyclic carbenes (NHCs) have emerged as a powerful class of organocatalysts that mediate a variety of organic transformations. The Benzoin reaction constitutes one of the earliest known carbon–carbon bond-forming reactions catalysed by NHCs. The rapid growth of NHC catalysis in general has resulted in the development of a variety of benzoin and benzoin-type reactions. An overview of such NHC-catalysed benzoin reactions is presented.


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