A5RE4X[TO4]4crystal growth and photoluminescence. Fluoride flux synthesis of sodium and potassium rare earth silicate oxyfluorides

CrystEngComm ◽  
2015 ◽  
Vol 17 (25) ◽  
pp. 4654-4661 ◽  
Author(s):  
Allison M. Latshaw ◽  
Branford O. Wilkins ◽  
Kendall D. Hughey ◽  
Jeongho Yeon ◽  
Derek E. Williams ◽  
...  
Keyword(s):  
Rare Earth ◽  
Flux Synthesis ◽  
Fluoride Flux ◽  
Sodium And Potassium

Formation of Rare-Earth Element Phosphates in the Melts Based on the Equimolar Mixture of Sodium and Potassium Chlorides

2019 ◽  
Vol 2019 (2) ◽  
pp. 152-154
Author(s):  
A. B. Ivanov ◽  
V. V. Sukhikh ◽  
V. A. Volkovich ◽  
B. D. Vasin ◽  
A. V. Chukin
Keyword(s):  
Rare Earth ◽  
Rare Earth Element ◽  
Earth Element ◽  
Equimolar Mixture ◽  
Sodium And Potassium

scholarly journals Flux Synthesis, Crystal Structures, and Magnetic Ordering of the Rare-Earth Chromium(II) Oxyselenides RE2CrSe2O2 (RE = La–Nd)

2017 ◽  
Vol 56 (4) ◽  
pp. 2241-2247 ◽  
Author(s):  
Simon Peschke ◽  
Valentin Weippert ◽  
Anatoliy Senyshyn ◽  
Martin Johann Mühlbauer ◽  
Oliver Janka ◽  
...  
Keyword(s):  
Rare Earth ◽  
Crystal Structures ◽  
Magnetic Ordering ◽  
Flux Synthesis ◽  
The Rare Earth

Lead phosphate apatites substituted by rare earth, sodium, and potassium ions

1980 ◽  
Vol 34 (2) ◽  
pp. 223-229 ◽  
Author(s):  
I. Mayer ◽  
A. Semadja ◽  
V. Weiss
Keyword(s):  
Rare Earth ◽  
Potassium Ions ◽  
Lead Phosphate ◽  
Sodium And Potassium

Flux synthesis, crystal structure and electronic properties of the layered rare earth metal boride silicide Er3Si5–x B. An example of a boron/silicon-ordered structure derived from the AlB2 structure type

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Volodymyr Babizhetskyy ◽  
Régis Jardin ◽  
Régis Gautier ◽  
Bruno Fontaine ◽  
Jean-François Halet
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Density Functional ◽  
Earth Metal ◽  
Structure Type ◽  
Metal Boride ◽  
Ordered Structure ◽  
Flux Synthesis ◽  
Bonding Properties ◽  
Difference Fourier

Abstract The ternary rare earth metal boride silicide Er3Si5–x B (x = 1.17) was synthesized from the elements using the tin flux method. It crystallizes in a new structure type in the space group R32 (a = 6.5568(1) Å, c = 24.5541(1) Å, Z = 6). The structural arrangement can be derived from the AlB2 structure type with boron/silicon ordering in the layered metalloid substructure made of [Si5B] hexagons. The presence or absence of the boron atoms involved in this ordered structure is discussed on the basis of difference Fourier syntheses and structural analysis, in relation with the binary parent structures AlB2 and Yb3Si5 (Th3Pd5 type). The electronic and bonding properties of Er3Si5–x B were analyzed and discussed via density functional theory (DFT) calculations and a crystal orbital Hamiltonian population (COHP) bonding analysis.

Structure of rare earth phosphates formed in the melts based on the equimolar mixture of sodium and potassium chlorides

2018 ◽  
Author(s):  
V. V. Sukhikh ◽  
A. B. Ivanov ◽  
V. A. Volkovich ◽  
B. D. Vasin ◽  
A. V. Chukin ◽  
...  
Keyword(s):  
Rare Earth ◽  
Equimolar Mixture ◽  
Sodium And Potassium

Tin flux synthesis of rare-earth metal silicide compounds RESi1.7 (RE = Dy, Ho): a novel ordered structure derived from the AlB2 type

2006 ◽  
Vol 221 (5-7) ◽  
Author(s):  
Jérome Roger ◽  
Volodymyr Babizhetskyy ◽  
Régis Jardin ◽  
Roland Guérin ◽  
Claude Moinet ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Metal Silicide ◽  
Ordered Structure ◽  
Flux Synthesis ◽  
Metal Silicides ◽  
Silicide Compounds ◽  
Binary Rare Earth

AbstractThe binary rare-earth metal silicides RESi

ChemInform Abstract: A5RE4X[TO4]4Crystal Growth: Fluoride Flux Synthesis of Na5Ln4F[GeO4]4(Ln: Pr, Nd), the First Quaternary Germanate Oxyfluorides.

ChemInform ◽  
2016 ◽  
Vol 47 (31) ◽  
Author(s):  
Allison M. Latshaw ◽  
Branford O. Wilkins ◽  
Gregory Morrison ◽  
Mark D. Smith ◽  
Hans-Conrad zur Loye
Keyword(s):  
Flux Synthesis ◽  
Fluoride Flux

scholarly journals A5RE4X[TO4]4 crystal growth: Fluoride flux synthesis of Na5Ln4F[GeO4]4 (Ln=Pr, Nd), the first quaternary germanate oxyfluorides

2016 ◽  
Vol 239 ◽  
pp. 200-203 ◽  
Author(s):  
Allison M. Latshaw ◽  
Branford O. Wilkins ◽  
Gregory Morrison ◽  
Mark D. Smith ◽  
Hans-Conrad zur Loye
Keyword(s):  
Crystal Growth ◽  
Flux Synthesis ◽  
Fluoride Flux
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