Successive Grinding and Polishing Effect on the Retained Austenite in the Surface of 42CrMo4 Steel

Low-alloy 42CrMo4 steels were studied by 57Fe Mössbauer spectroscopy (MS), X-ray diffractometry (XRD), and Energy Dispersive X-ray Spectroscopy (EDS) measurements. The investigations were performed on metallographic samples, which were subjected to a series of successive grinding and polishing with a progressively finer grit. Conversion X-ray Mössbauer spectroscopy (CXMS) was used to determine the occurrence of austenite in steel samples. It is a unique method detecting the austenite content very sensitively. Six samples with different surface preparation were investigated, starting with 4.8% of austenite on an as-cut sample, and a large decrease in the retained austenite to 2.6% was observed after the first grinding of a hardened cut sample. Additionally, an unexpectedly large decrease in the austenite content to 2.3% was found due to the final polishing. A second time applied successive grinding and polishing of all samples resulted in identical austenite content determined by CXMS of approx. 5%, which proved the applicability of the CXMS method. Generally, the result calls attention to the importance of preparation of metallurgical samples by grinding and polishing where the results can vary significantly on the level of surface processing.

4M method – new application of Mössbauer spectroscopy to classification of meteorites. How it works?

Abstract4M method is a new application of Mössbauer spectroscopy to quantitative classification of ordinary chondrites. 4M derives from four words: meteorites, Mössbauer spectroscopy, multidimensional discriminant analysis, Mahalanobis distance. This method was published by us in 2019. In this paper we present application of 4M method to classification of four meteorites. Link to script with calculation needed for classification of ordinary chondrites was given.