Electronic structures and second hyperpolarizabilities of alkaline earth metal complexes end-capped with NA2 (A = H, Li, Na)

2016 ◽  
Vol 18 (18) ◽  
pp. 12505-12520 ◽  
Author(s):  
Paramita Banerjee ◽  
Prasanta K. Nandi
Keyword(s):  
Metal Complexes ◽  
Ground State ◽  
Electronic Structures ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Basis Sets ◽  
Alkaline Earth Metal ◽  
Nlo Properties ◽  
Ground State Structures

The ground state structures and NLO properties of a number of alkaline earth metal complexes end-capped with NA2 groups (A = H, Li, Na) are calculated by employing the CAM-B3LYP, wB97XD and B2PLYP functionals along with MP2 and CCSD(T) for 6-311++G(d,p), 6-311++G(3df,3pd), aug-cc-pVTZ, aug-pc-2 and Hypol basis sets.

C–H and C–F coordination of arenes in neutral alkaline earth metal complexes

2021 ◽  
Author(s):  
Jacob S. McMullen ◽  
Alison J. Edwards ◽  
Jamie Hicks
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Calcium Complexes ◽  
Group 2 ◽  
Rare Group

A series of neutral magnesium and calcium complexes bearing an extremely bulky diamido ligand have been synthesised and crystallographically characterised. A number of these complexes feaure rare group 2 metal···aromatic...

Alkali and alkaline-earth metal complexes of different nuclearities with azamacrocyclic pendant-arms ligands

2009 ◽  
Vol 362 (9) ◽  
pp. 3351-3356 ◽  
Author(s):  
Luis Botana ◽  
Rufina Bastida ◽  
Alejandro Macías ◽  
Paulo Pérez-Lourido ◽  
Laura Valencia
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Pendant Arms

Highly Lewis acidic cationic alkaline earth metal complexes

2018 ◽  
Vol 54 (63) ◽  
pp. 8685-8688 ◽  
Author(s):  
Jürgen Pahl ◽  
Steffen Brand ◽  
Holger Elsen ◽  
Sjoerd Harder
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal

“Naked” cationic β-diketiminate Mg and Ca complexes possess high Lewis acidities and bind strongly to neutral benzene or alkyne ligands.

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