Bis(alkyl) rare-earth complexes supported by a new tridentate amidinate ligand with a pendant diphenylphosphine oxide group. Synthesis, structures and catalytic activity in isoprene polymerization
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The introduction of a pendant Ph2P(O) group into an amidinate ligand resulted in high 1,4-cis selectivity (96.6%) while maintaining very high activity.
2012 ◽
Vol 2012
(13)
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pp. 2289-2297
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2016 ◽
Vol 65
(12)
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pp. 2832-2840
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