A solution-processed, mercaptoacetic acid-engineered CdSe quantum dot photocathode for efficient hydrogen production under visible light irradiation

2015 ◽  
Vol 8 (5) ◽  
pp. 1443-1449 ◽  
Author(s):  
Bin Liu ◽  
Xu-Bing Li ◽  
Yu-Ji Gao ◽  
Zhi-Jun Li ◽  
Qing-Yuan Meng ◽  
...  

We describe a simple, efficient and stable mercaptoacetic acid-engineered CdSe quantum dot photocathode for hydrogen generation by water-splitting from neutral water.

2020 ◽  
Vol 16 ◽  
Author(s):  
Yuxue Wei ◽  
Honglin Qin ◽  
Jinxin Deng ◽  
Xiaomeng Cheng ◽  
Mengdie Cai ◽  
...  

Introduction: Solar-driven photocatalytic hydrogen production from water splitting is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. In this review, recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. In particular, the factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Background: Photocatalytic hydrogen evolution from water splitting using photocatalyst semiconductors is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. Methods: This review summarizes the recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation. Results: Recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. The factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Conclusion: The state-of-the-art CdS for producing hydrogen from photocatalytic water splitting under visible light is discussed. The future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are also described.


RSC Advances ◽  
2014 ◽  
Vol 4 (68) ◽  
pp. 35997-36005 ◽  
Author(s):  
Rajeev C. Chikate ◽  
Brijesh S. Kadu ◽  
Madhura A. Damle

Intercalated CdSe–CTAB–MMT nanocomposites with uniform dispersion of CdSe QD's are fabricated by a facile self-assembly approach that significantly enhances visible light induced photocatalytic degradation of Indigo Carmine.


2019 ◽  
Vol 6 (7) ◽  
pp. 1753-1760 ◽  
Author(s):  
Anbu Kumaresan ◽  
Shuo Yang ◽  
Kun Zhao ◽  
Nafees Ahmad ◽  
Jiyu Zhou ◽  
...  

The facile development of CoAl-LDHs/RGO nanocomposites as photocatalysts for efficient hydrogen generation from water splitting under visible-light irradiation.


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