Ring-opening polymerization of lactide using chiral salen aluminum complexes as initiators: high productivity and stereoselectivity

2015 ◽  
Vol 39 (6) ◽  
pp. 4670-4675 ◽  
Author(s):  
Bo Gao ◽  
Dongni Li ◽  
Yanhui Li ◽  
Qian Duan ◽  
Ranlong Duan ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
High Productivity ◽  
Aluminum Complexes ◽  
Salen Aluminum ◽  
Lactide Polymerization

Chiral salen aluminum complexes have been synthesized and investigated as initiators for l-lactide and rac-lactide polymerization.

Synthesis of biodegradable and biorenewable polylactides initiated by aluminum complexes bearing m-xylylenediamine derivatives via the ring-opening polymerization of lactides

2019 ◽  
Vol 43 (18) ◽  
pp. 6943-6950 ◽  
Author(s):  
Dongni Li ◽  
Bo Gao ◽  
Qian Duan
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Aluminum Complexes ◽  
Lactide Polymerization

Aluminum complexes derived from m-xylylenediamine were synthesized and investigated as initiators for l-lactide and rac-lactide polymerization.

Preparation of biocompatible, biodegradable and sustainable polylactides catalyzed by aluminum complexes bearing unsymmetrical dinaphthalene-imine derivatives via ring-opening polymerization of lactides

2015 ◽  
Vol 5 (9) ◽  
pp. 4644-4652 ◽  
Author(s):  
Bo Gao ◽  
Dongni Li ◽  
Xiang Li ◽  
Ranlong Duan ◽  
Xuan Pang ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Aluminum Complexes ◽  
Imine Ligands ◽  
Lactide Polymerization

Aluminum complexes bearing unsymmetrical dinaphthalene-imine ligands were employed for lactide polymerization.

Bimetallic salen aluminum complexes: cooperation between reactive centers in the ring-opening polymerization of lactides and epoxides

2016 ◽  
Vol 45 (40) ◽  
pp. 16001-16010 ◽  
Author(s):  
Florence Isnard ◽  
Marina Lamberti ◽  
Luana Lettieri ◽  
Ilaria D'auria ◽  
Konstantin Press ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Aluminum Complexes ◽  
Catalytic Performances ◽  
Salen Aluminum

In dinuclear aluminum complexes, opportunely designed to have proximal coordinative pockets, the communication between the two reactive centers allows enhanced catalytic performances.

Synthesis and characterization of neutral and cationic aluminum complexes supported by a furfuryl-containing aminophenolate ligand for ring-opening polymerization of ε-caprolactone

2018 ◽  
Vol 42 (11) ◽  
pp. 8374-8383 ◽  
Author(s):  
Jiraya Kiriratnikom ◽  
Sucheewin Chotchatchawankul ◽  
Setsiri Haesuwannakij ◽  
Supavadee Kiatisevi ◽  
Khamphee Phomphrai
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Synthesis And Characterization ◽  
Aluminum Complexes

Mononuclear aluminum complexes supported by novel furfuryl-containing aminophenolate ligand are reported along with CL polymerization.

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