Alkoxyamine-functionalized latex nanoparticles through RAFT polymerization-induced self-assembly in water

2015 ◽  
Vol 6 (30) ◽  
pp. 5405-5413 ◽  
Author(s):  
Claude St Thomas ◽  
Ramiro Guerrero-Santos ◽  
Franck D'Agosto
Keyword(s):  
Acrylic Acid ◽  
Self Assembly ◽  
Raft Polymerization ◽  
Poly Acrylic Acid

Alkoxyamine-functionalized latex nanoparticles were obtained through RAFT polymerization-induced self-assembly in water using poly(acrylic acid) macroRAFT carrying alkoxyamine moieties.

Synthesis of poly(methyl methacrylate)-b-poly(acrylic acid) by DPE method

e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Dong Chen ◽  
Ruixue Liu ◽  
Zhifeng Fu ◽  
Yan Shi
Keyword(s):  
Molecular Weight ◽  
Acrylic Acid ◽  
Methyl Methacrylate ◽  
Diblock Copolymer ◽  
Self Assembly ◽  
Gel Permeation Chromatography ◽  
Amphiphilic Diblock Copolymer ◽  
Poly Methyl Methacrylate ◽  
Copolymer Poly ◽  
Poly Acrylic Acid

AbstractAmphiphilic diblock copolymer poly(methyl methacrylate)-b-poly(acrylic acid) (PMMA-b-PAA) was prepared by 1,1-diphenylethene (DPE) method. Firstly, free radical polymerization of methyl methacrylate was carried out with AIBN as initiator in the presence of DPE, giving a DPE-containing PMMA precursor with controlled molecular weight. tert-Butyl acrylate (tBA) was then polymerized in the presence of the PMMA precursor, and PMMA-b-PtBA diblock copolymer with controlled molecular weight was prepared. Finally, amphiphilic diblock copolymer PMMA-b-PAA was obtained by hydrolysis of PMMA-b-PtBA. The formation of PMMA-b-PAA was confirmed by 1H NMR spectrum and gel permeation chromatography. Transmission electron microscopy and dynamic light scattering were used to detect the self-assembly behavior of the amphiphilic diblock polymers in methanol.

CO2-Triggered and temperature-switchable crystallization-driven self-assembly of a semicrystalline block copolymer in aqueous medium

2019 ◽  
Vol 10 (46) ◽  
pp. 6305-6314
Author(s):  
Rui Zhu ◽  
Xinjie Luo ◽  
Yujun Feng ◽  
Laurent Billon
Keyword(s):  
Block Copolymer ◽  
Acrylic Acid ◽  
Aqueous Medium ◽  
Self Assembly ◽  
Pure Block ◽  
Random Block ◽  
Nitroxide Mediated Polymerization ◽  
Poly Acrylic Acid

The synthesis of a semicrystalline block copolymer comprising a hydrophilic poly(acrylic acid) pure block and an amphiphilic poly(acrylic acid)-r-poly(octadecyl acrylate) random block by nitroxide-mediated polymerization is reported.

Dual stimuli-responsive N-phthaloylchitosan-graft-(poly(N-isopropylacrylamide)-block-poly(acrylic acid)) copolymer prepared via RAFT polymerization

2013 ◽  
Vol 92 (1) ◽  
pp. 662-667 ◽  
Author(s):  
Ke Zhang ◽  
Zhengke Wang ◽  
Youliang Li ◽  
Zhiqiang Jiang ◽  
Qiaoling Hu ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Raft Polymerization ◽  
Stimuli Responsive ◽  
Acid Copolymer ◽  
Acrylic Acid Copolymer ◽  
Poly Acrylic Acid

Ab Initio Batch Emulsion RAFT Polymerization of Styrene Mediated by Poly(acrylic acid-b-styrene) Trithiocarbonate

2009 ◽  
Vol 42 (17) ◽  
pp. 6414-6421 ◽  
Author(s):  
Xiaoguang Wang ◽  
Yingwu Luo ◽  
Bogeng Li ◽  
Shiping Zhu
Keyword(s):  
Acrylic Acid ◽  
Ab Initio ◽  
Raft Polymerization ◽  
Poly Acrylic Acid

scholarly journals Synthesis of amphiphilic copolymers based on acrylic acid, fluoroalkyl acrylates and n-butyl acrylate in organic, aqueous–organic, and aqueous media via RAFT polymerization

RSC Advances ◽  
2017 ◽  
Vol 7 (39) ◽  
pp. 24522-24536 ◽  
Author(s):  
N. S. Serkhacheva ◽  
O. I. Smirnov ◽  
A. V. Tolkachev ◽  
N. I. Prokopov ◽  
A. V. Plutalova ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Polyacrylic Acid ◽  
Self Assembly ◽  
Butyl Acrylate ◽  
Raft Polymerization ◽  
Aqueous Media ◽  
Amphiphilic Copolymers

Hydrophilic and amphiphilic polymeric trithiocarbonates based on polyacrylic acid are able to provide polymerization-induced self-assembly in copolymerization of butyl and fluoroalkyl acrylates.

RAFT Polymerization of 1-Ethoxyethyl Acrylate:  A Novel Route toward Near-Monodisperse Poly(acrylic acid) and Derived Block Copolymer Structures

2005 ◽  
Vol 38 (18) ◽  
pp. 7653-7659 ◽  
Author(s):  
Richard Hoogenboom ◽  
Ulrich S. Schubert ◽  
Wim Van Camp ◽  
Filip E. Du Prez
Keyword(s):  
Block Copolymer ◽  
Acrylic Acid ◽  
Raft Polymerization ◽  
Poly Acrylic Acid

scholarly journals Effect of the pH on the RAFT Polymerization of Acrylic Acid in Water. Application to the Synthesis of Poly(acrylic acid)-Stabilized Polystyrene Particles by RAFT Emulsion Polymerization

2013 ◽  
Vol 46 (15) ◽  
pp. 6013-6023 ◽  
Author(s):  
Isabelle Chaduc ◽  
Agnès Crepet ◽  
Olivier Boyron ◽  
Bernadette Charleux ◽  
Franck D’Agosto ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Emulsion Polymerization ◽  
Raft Polymerization ◽  
Water Application ◽  
Poly Acrylic Acid
Sign in / Sign up

Export Citation Format

Share Document