A mechanistic study on the SHi reaction at tin atoms in a radical cascade reaction

2015 ◽  
Vol 2 (6) ◽  
pp. 713-720 ◽  
Author(s):  
Akio Kamimura ◽  
Tatsuro Yoshinaga ◽  
Fumiaki Noguchi ◽  
Koichiro Miyazaki ◽  
Hidemitsu Uno
Keyword(s):  
Kinetic Study ◽  
Substitution Reaction ◽  
Cascade Reaction ◽  
Mechanistic Study ◽  
Radical Cascade ◽  
Radical Substitution ◽  
Radical Substitution Reaction

A kinetic study on the intramolecular direct radical substitution reaction on tin atoms was undertaken.

Nucleophilic Radical Substitution Reaction of Triazine Herbicides with Polysulfides

2004 ◽  
Vol 52 (23) ◽  
pp. 7051-7055 ◽  
Author(s):  
Weichun Yang ◽  
Jay J. Gan ◽  
Svetlana Bondarenko ◽  
Weiping Liu
Keyword(s):  
Substitution Reaction ◽  
Triazine Herbicides ◽  
Radical Substitution ◽  
Radical Substitution Reaction

scholarly journals Mechanistic study on substitution reaction of a citrato(p-cymene)Ru(ii) complex with sulfur-containing amino acids

RSC Advances ◽  
2019 ◽  
Vol 9 (43) ◽  
pp. 25177-25183
Author(s):  
Sen-ichi Aizawa ◽  
Kohei Takizawa ◽  
Momoko Aitani
Keyword(s):  
Amino Acids ◽  
Reaction Mechanism ◽  
Kinetic Study ◽  
Substitution Reaction ◽  
Mechanistic Study ◽  
Sulfur Containing

Thorough kinetic study revealed characteristics of the reaction mechanism for arene ruthenium(ii) complexes with bio-related ligands.

The Oxidation of (±)-Reticuline as Studied by E.S.R Spectroscopy

1985 ◽  
Vol 38 (3) ◽  
pp. 497 ◽  
Author(s):  
FR Hewgill ◽  
MC Pass
Keyword(s):  
Substitution Reaction ◽  
Flow System ◽  
Radical Substitution ◽  
Related Compounds ◽  
Radical Substitution Reaction

E.s.r. spectra obtained by oxidation of reticuline and closely related compounds in a flow system with cerium(IV) show chiefly the aryloxy radical derived from the 1-benzyl c-ring. The 4′-ethoxy homologue of norreticuline shows both A- and C-ring radicals in roughly equal proportions. The mechanism of intramolecular coupling is discussed, and as no evidence was obtained for the occurrence of a radical substitution reaction it is concluded that radical pairing is more likely, although this apparently happens too quickly for observation of a biradical species.

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