Biomimetic mineralization of metal–organic frameworks around polysaccharides

2017 ◽  
Vol 53 (7) ◽  
pp. 1249-1252 ◽  
Author(s):  
Kang Liang ◽  
Ru Wang ◽  
Manon Boutter ◽  
Cara M. Doherty ◽  
Xavier Mulet ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Functional Materials ◽  
Biomimetic Mineralization ◽  
Metal Organic

Biomimetic mineralization exploits natural biomineralization processes for the design and fabrication of synthetic functional materials.

Metal-Organic Frameworks: New Functional Materials and Applications

2019 ◽  
pp. 35-54
Author(s):  
Peiyu Cai ◽  
Wenmiao Chen ◽  
Gregory S. Day ◽  
Hannah F. Drake ◽  
Elizabeth A. Joseph ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Functional Materials ◽  
Metal Organic

scholarly journals Gas Adsorption Selectivity in Topologically Disordered Metal–Organic Frameworks

2021 ◽  
Author(s):  
Adam Sapnik ◽  
Christopher W. Ashling ◽  
Lauren K. Macreadie ◽  
Seok J. Lee ◽  
Tim Johnson ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Interaction Strength ◽  
Functional Materials ◽  
Adsorption Selectivity ◽  
Guest Molecules ◽  
Sorption Behaviour ◽  
Ideal Adsorbed Solution Theory ◽  
Industrial Gases ◽  
Metal Organic

<div><p>Disordered metal–organic frameworks are emerging as an attractive class of functional materials, however their applications in gas storage and separation have yet to be fully explored. Here, we investigate gas adsorption in the topologically disordered Fe-BTC framework and its crystalline counterpart, MIL‑100. Despite their similar chemistry and local structure, they exhibit very different sorption behaviour towards a range of industrial gases, noble gases and hydrocarbons. Virial analysis reveals that Fe-BTC has enhanced interaction strength with guest molecules compared to MIL‑100. Most notably, we observe striking discrimination between the adsorption of C<sub>3</sub>H<sub>6</sub> and C<sub>3</sub>H<sub>8</sub> in Fe‑BTC, with over a twofold increase in the amount of C<sub>3</sub>H<sub>6</sub> being adsorbed than C<sub>3</sub>H<sub>8</sub>. Thermodynamic selectivity towards a range of industrially relevant binary mixtures is probed using ideal adsorbed solution theory (IAST). Together, this suggests the disordered material may possess powerful separation capabilities that are rare even amongst crystalline frameworks.</p></div>

Deuterohemin-Peptide Enzyme Mimic-Embedded Metal-Organic Frameworks through Biomimetic Mineralization with Efficient ATRP Catalytic Activity

2017 ◽  
Vol 9 (32) ◽  
pp. 26948-26957 ◽  
Author(s):  
Wei Jiang ◽  
Xinghuo Wang ◽  
Jiawen Chen ◽  
Ying Liu ◽  
Haobo Han ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Frameworks ◽  
Enzyme Mimic ◽  
Biomimetic Mineralization ◽  
Metal Organic

ChemInform Abstract: Giant Metal-Organic Frameworks with Bulky Scaffolds: From Microporous to Mesoporous Functional Materials

ChemInform ◽  
2012 ◽  
Vol 43 (26) ◽  
pp. no-no
Author(s):  
Pounraj Thanasekaran ◽  
Tzuoo-Tsair Luo ◽  
Jing-Yun Wu ◽  
Kuang-Lieh Lu
Keyword(s):  
Metal Organic Frameworks ◽  
Functional Materials ◽  
Metal Organic

scholarly journals Gas adsorption in the topologically disordered Fe-BTC framework

2021 ◽  
Author(s):  
Adam Sapnik ◽  
Christopher W. Ashling ◽  
Lauren Macreadie ◽  
Seok J. Lee ◽  
Timothy Johnson ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Functional Materials ◽  
Gas Storage ◽  
Metal Organic

Disordered metal–organic frameworks are emerging as an attractive class of functional materials, however their applications in gas storage and separation have yet to be fully explored. Here, we investigate gas...

Giant metal–organic frameworks with bulky scaffolds: from microporous to mesoporous functional materials

2012 ◽  
Vol 41 (18) ◽  
pp. 5437 ◽  
Author(s):  
Pounraj Thanasekaran ◽  
Tzuoo-Tsair Luo ◽  
Jing-Yun Wu ◽  
Kuang-Lieh Lu
Keyword(s):  
Metal Organic Frameworks ◽  
Functional Materials ◽  
Metal Organic

Cobalt-based metal-organic frameworks as functional materials for battery applications

CrystEngComm ◽  
2021 ◽  
Author(s):  
Hong Ou ◽  
Qiongyi Xie ◽  
Qingyun Yang ◽  
Jianen Zhou ◽  
Akif Zeb ◽  
...  
Keyword(s):  
Energy Storage ◽  
Metal Organic Frameworks ◽  
Functional Materials ◽  
Electrochemical Energy Storage ◽  
Energy Storage And Conversion ◽  
Metal Organic ◽  
Electrochemical Energy

In recent years, metal-organic frameworks (MOFs) have been widely used in various fields, especially electrochemical energy storage and conversion area, because of their excellent properties. It is reported that the...

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