Construction of Thermophilic Lipase-Embedded Metal–Organic Frameworks via Biomimetic Mineralization: A Biocatalyst for Ester Hydrolysis and Kinetic Resolution

2016 ◽  
Vol 8 (37) ◽  
pp. 24517-24524 ◽  
Author(s):  
Hongming He ◽  
Haobo Han ◽  
Hui Shi ◽  
Yuyang Tian ◽  
Fuxing Sun ◽  
...  
Keyword(s):  
Kinetic Resolution ◽  
Metal Organic Frameworks ◽  
Ester Hydrolysis ◽  
Biomimetic Mineralization ◽  
Metal Organic ◽  
Thermophilic Lipase

Biomimetic mineralization of metal–organic frameworks around polysaccharides

2017 ◽  
Vol 53 (7) ◽  
pp. 1249-1252 ◽  
Author(s):  
Kang Liang ◽  
Ru Wang ◽  
Manon Boutter ◽  
Cara M. Doherty ◽  
Xavier Mulet ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Functional Materials ◽  
Biomimetic Mineralization ◽  
Metal Organic

Biomimetic mineralization exploits natural biomineralization processes for the design and fabrication of synthetic functional materials.

Deuterohemin-Peptide Enzyme Mimic-Embedded Metal-Organic Frameworks through Biomimetic Mineralization with Efficient ATRP Catalytic Activity

2017 ◽  
Vol 9 (32) ◽  
pp. 26948-26957 ◽  
Author(s):  
Wei Jiang ◽  
Xinghuo Wang ◽  
Jiawen Chen ◽  
Ying Liu ◽  
Haobo Han ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Frameworks ◽  
Enzyme Mimic ◽  
Biomimetic Mineralization ◽  
Metal Organic

scholarly journals A General Approach for Encapsulation of Biomolecules Using MOF Particles

2020 ◽  
Author(s):  
Da Zou ◽  
Lei Yu ◽  
Qi Sun ◽  
Yue Hui ◽  
Teng Jisi ◽  
...  
Keyword(s):  
Drug Delivery ◽  
Room Temperature ◽  
Metal Organic Frameworks ◽  
General Strategy ◽  
Biomimetic Mineralization ◽  
Mineralization Process ◽  
Chemical Reagents ◽  
Significant Interest ◽  
Benign Process ◽  
Metal Organic

Encapsulation of biomoleucles in metal organic frameworks (MOFs) has recently attracted significant interest because of the benign process including room temperature, neutral pH and without the requirement of any other chemical reagents. Also, these biomolecule incorporated MOFs (biomolecules@MOFs) have demonstrated their potential in biomolecule protection and controlled release for various applications such as drug delivery, vaccines, etc. This work aims to develop a general strategy to make biomolecules@MOFs via a biomimetic mineralization process.

scholarly journals Triazolium-Containing Metal–Organic Frameworks: Control of Catenation in 2D Copper(II) Paddlewheel Structures

2013 ◽  
Vol 66 (4) ◽  
pp. 409 ◽  
Author(s):  
Alexandre Burgun ◽  
Christian J. Doonan ◽  
Christopher J. Sumby
Keyword(s):  
Benzoic Acid ◽  
Heterogeneous Catalyst ◽  
Click Reaction ◽  
Metal Organic Frameworks ◽  
Ester Hydrolysis ◽  
Charge Balance ◽  
Reaction Conditions ◽  
Metal Organic ◽  
Methyl Triflate

One approach to exploit metal–organic frameworks (MOFs) as heterogeneous catalyst platforms requires the development of materials containing groups that can be utilised to anchor a catalytic moiety into the links within the structure. Here we report the synthesis of the first integrated triazolium-containing MOF linker and the first MOFs containing linkers of this type. 1,4-Bis(4-benzoic acid)-1-methyl-1H-1,2,3-triazolium chloride, H2L1Me, was synthesised in three steps by a ‘click’ reaction of methyl 4-ethynylbenzoate with methyl 4-azidobenzoate, methylation using methyl triflate, followed by ester hydrolysis in overall 74 % yield. The equivalent neutral triazole precursor, 1,4-bis(4-benzoic acid)-1H-1,2,3-triazole hydrochloride, H2L1(HCl), was also prepared and a comparison of the chemistry with Zn(NO3)2·6H2O and Cu(NO3)2·3H2O is presented. The results support the use of reaction conditions to control interpenetration and provide additional evidence that the charge on structurally similar ligands can drastically alter the types of structures that are accessible due to the requirements for charge balance in the final product.

Nanoscale dual-enzyme cascade metal–organic frameworks through biomimetic mineralization as ROS generators for synergistic cancer therapy

2020 ◽  
Vol 8 (21) ◽  
pp. 4620-4626
Author(s):  
Shuiling Jin ◽  
Lanling Weng ◽  
Zhi Li ◽  
Zhenzhen Yang ◽  
Lili Zhu ◽  
...  
Keyword(s):  
Reactive Oxygen Species ◽  
Cancer Therapy ◽  
Metal Organic Frameworks ◽  
Reactive Oxygen ◽  
Ros Production ◽  
Oxygen Species ◽  
Biomimetic Mineralization ◽  
Enzyme Cascade ◽  
Metal Organic ◽  
Cancer Tissues

Chemodynamic therapy (CDT) has been critically challenged by insufficient H2O2 in cancer tissues and inefficient reactive oxygen species (ROS) production.

scholarly journals Biomimetic mineralization of metal-organic frameworks as protective coatings for biomacromolecules

2015 ◽  
Vol 6 (1) ◽  
Author(s):  
Kang Liang ◽  
Raffaele Ricco ◽  
Cara M. Doherty ◽  
Mark J. Styles ◽  
Stephen Bell ◽  
...  
Keyword(s):  
Protective Coatings ◽  
Metal Organic Frameworks ◽  
Biomimetic Mineralization ◽  
Metal Organic
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