scholarly journals Secondary amine-functionalised metal–organic frameworks: direct syntheses versus tandem post-synthetic modifications

CrystEngComm ◽  
2016 ◽  
Vol 18 (30) ◽  
pp. 5710-5717 ◽  
Author(s):  
Luke L. Keenan ◽  
Harina Amer Hamzah ◽  
Mary F. Mahon ◽  
Mark R. Warren ◽  
Andrew D. Burrows
Keyword(s):  
Dicarboxylic Acid ◽  
Secondary Amine ◽  
Direct Synthesis ◽  
Metal Organic Frameworks ◽  
Metal Organic

We compare two routes to prepare functionalised MOFs and show that direct synthesis with a functionalised dicarboxylic acid is better for zinc MOFs whereas post-synthetic modification is better for chromium MOFs.

Two dimethylphenyl imidazole dicarboxylate-based lanthanide metal–organic frameworks for luminescence sensing of benzaldehyde

2015 ◽  
Vol 44 (9) ◽  
pp. 4362-4369 ◽  
Author(s):  
Bingbing Shi ◽  
Yuanhao Zhong ◽  
Lili Guo ◽  
Gang Li
Keyword(s):  
Dicarboxylic Acid ◽  
Metal Organic Frameworks ◽  
Hydrothermal Conditions ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Imidazole Dicarboxylate

Two novel dimethylphenyl imidazole dicarboxylate-based lanthanide(iii)-organic frameworks, [Ln(H2DMPhIDC)3(H3DMPhIDC)]n (Ln = Eu (1), Tb (2); H3DMPhIDC = 2-(3,4-dimethylphenyl)-1H-imidazole-4,5-dicarboxylic acid) have been synthesized under hydrothermal conditions.

Assembly of porous lanthanide metal–organic frameworks constructed by chalcone dicarboxylic acid and exploration of their properties

Polyhedron ◽  
2019 ◽  
Vol 169 ◽  
pp. 24-31 ◽  
Author(s):  
Wei Pan ◽  
Chunhua Gong ◽  
Xianghua Zeng ◽  
Chenyan Hu ◽  
Yi Zhang ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Lanthanide Metal

One-dimensional (1D) helical and 2D homochiral metal–organic frameworks built from a new chiral octahydrobinaphthalene-derived dicarboxylic acid

2008 ◽  
Vol 11 (9) ◽  
pp. 948-950 ◽  
Author(s):  
Xiang Ouyang ◽  
Zhenxia Chen ◽  
Xiaofeng Liu ◽  
Yongtai Yang ◽  
Mingli Deng ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Metal Organic Frameworks ◽  
One Dimensional ◽  
Metal Organic

scholarly journals Two-dimensional metal-organic frameworks containing linear dicarboxylates

2006 ◽  
Vol 62 (5) ◽  
pp. 808-814 ◽  
Author(s):  
Samuel M. Hawxwell ◽  
Harry Adams ◽  
Lee Brammer
Keyword(s):  
Dicarboxylic Acid ◽  
Solvothermal Synthesis ◽  
Interplanar Spacing ◽  
Metal Organic Frameworks ◽  
Dicarboxylic Acids ◽  
Two Dimensional ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Gas Molecules ◽  
Solvent Molecules

The solvothermal synthesis of four two-dimensional metal-organic frameworks containing linear dicarboxylic acids as ligands for ZnII centres is described. Zn(BDC)(DMF) [(1) where BDC = benzene-1,4-dicarboxylic acid; DMF = N,N-dimethylformamide] adopts a common paddlewheel motif leading to a 44 grid network, whereas Zn3(BDC)3(EtOH)2 (2), Zn3(BDC)3(H2O)2·4DMF (3) and Zn3(BPDC)3(DMF)2·4DMF (4) each form networks with the relatively uncommon 36 topology based upon Zn3(O2CR)6 secondary building units. All contain coordinated solvent molecules, namely DMF [(1) and (4)], ethanol (2) or H2O (3). Comparison of structures (2) and (3) illustrates a clay-like flexibility in interplanar spacing which sheds light on the ability of the Zn3(BDC)3 framework to undergo desolvation and uptake of small solvent and gas molecules.

New metal–organic frameworks derived from pyridine-3,5-dicarboxylic acid: structural diversity arising from the addition of templates into the reaction systems

CrystEngComm ◽  
2020 ◽  
Vol 22 (11) ◽  
pp. 2083-2096 ◽  
Author(s):  
Eleni E. Moushi ◽  
Andreas Kourtellaris ◽  
Eleni Andreou ◽  
Athina Fidelli ◽  
Giannis S. Papaefstathiou ◽  
...  
Keyword(s):  
Metal Ions ◽  
Dicarboxylic Acid ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Structural Diversity ◽  
Reaction Systems ◽  
Metal Organic

The effect of aminoalcohol/polyol template molecules in the formation of MOFs based on bipositive metal ions and pyridine-3,5-dicalboxylate ligand was investigated providing access to a series of new multidimensional coordination polymers.

scholarly journals Metal–organic frameworks constructed from crown ether-based 1,4-benzenedicarboxylic acid derivatives

2016 ◽  
Vol 45 (7) ◽  
pp. 3063-3069 ◽  
Author(s):  
Teng-Hao Chen ◽  
Andreas Schneemann ◽  
Roland A. Fischer ◽  
Seth M. Cohen
Keyword(s):  
Crown Ether ◽  
Dicarboxylic Acid ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Thiacrown Ether ◽  
Benzenedicarboxylic Acid ◽  
Metal Organic ◽  
Benzene Dicarboxylic Acid ◽  
Organic Framework

A series of crown ether- and thiacrown ether-derivatized benzene dicarboxylic acid (H2bdc) ligands has been synthesized and incorporated into the prototypical isoreticular metal–organic framework (IRMOF) and UiO-66 materials.

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