Quantum chemical clarification of the alkyl chain length threshold of nonionic surfactants for monolayer formation at the air/water interface

2016 ◽  
Vol 18 (11) ◽  
pp. 7932-7937
Author(s):  
Yu. B. Vysotsky ◽  
E. S. Kartashynska ◽  
E. A. Belyaeva ◽  
D. Vollhardt ◽  
V. B. Fainerman ◽  
...  
Keyword(s):  
Chain Length ◽  
Quantum Chemical ◽  
Theoretical Basis ◽  
Nonionic Surfactants ◽  
Alkyl Chain ◽  
Alkyl Chain Length ◽  
Experimental Fact ◽  
Water Interface ◽  
Monolayer Formation ◽  
Air Water Interface

A theoretical basis is introduced for the experimental fact that for various surfactant classes the alkyl chain length threshold varies for the formation of condensed monolayers.

The Formation of Surface Multilayers at the Air–Water Interface from Sodium Diethylene Glycol Monoalkyl Ether Sulfate/AlCl3 Solutions: The Role of the Alkyl Chain Length

Langmuir ◽  
2013 ◽  
Vol 29 (41) ◽  
pp. 12744-12753 ◽  
Author(s):  
Hui Xu ◽  
Jeffrey Penfold ◽  
Robert K. Thomas ◽  
Jordan T. Petkov ◽  
Ian Tucker ◽  
...  
Keyword(s):  
Chain Length ◽  
Diethylene Glycol ◽  
Alkyl Chain ◽  
Alkyl Chain Length ◽  
Water Interface ◽  
Ether Sulfate ◽  
Air Water Interface

Quantum-chemical analysis of hexagonal crystalline monolayers of ethoxylated nonionic surfactants at the air/water interface

2014 ◽  
Vol 16 (45) ◽  
pp. 25129-25142 ◽  
Author(s):  
Elena S. Kartashynska ◽  
Yuri B. Vysotsky ◽  
Elena A. Belyaeva ◽  
Valentin B. Fainerman ◽  
Dieter Vollhardt ◽  
...  
Keyword(s):  
Chemical Analysis ◽  
Quantum Chemical ◽  
Nonionic Surfactants ◽  
Water Interface ◽  
Quantum Chemical Analysis ◽  
Air Water Interface

Temperature Effect on the Monolayer Formation of Substituted Alkanes at the Air/Water Interface: A Quantum Chemical Approach

2012 ◽  
Vol 116 (30) ◽  
pp. 8996-9006 ◽  
Author(s):  
Yu. B. Vysotsky ◽  
E. S. Fomina ◽  
E. A. Belyaeva ◽  
D. Vollhardt ◽  
V. B. Fainerman ◽  
...  
Keyword(s):  
Temperature Effect ◽  
Quantum Chemical ◽  
Water Interface ◽  
Monolayer Formation ◽  
Chemical Approach ◽  
Air Water Interface ◽  
Quantum Chemical Approach ◽  
Substituted Alkanes
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