scholarly journals Efficient and selective oxidation of sulfur mustard using singlet oxygen generated by a pyrene-based metal–organic framework

2016 ◽  
Vol 4 (36) ◽  
pp. 13809-13813 ◽  
Author(s):  
Yangyang Liu ◽  
Cassandra T. Buru ◽  
Ashlee J. Howarth ◽  
John J. Mahle ◽  
James H. Buchanan ◽  
...  
Keyword(s):  
Singlet Oxygen ◽  
Selective Oxidation ◽  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Uv Led ◽  
Metal Organic ◽  
Led Irradiation ◽  
Organic Framework

Singlet oxygen generated by a metal–organic framework under UV LED irradiation selectively oxidizes sulfur mustard to nontoxic products.

Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal-Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard

2016 ◽  
Vol 23 (1) ◽  
pp. 214-218 ◽  
Author(s):  
Ashlee J. Howarth ◽  
Cassandra T. Buru ◽  
Yangyang Liu ◽  
Ann M. Ploskonka ◽  
Karel J. Hartlieb ◽  
...  
Keyword(s):  
Singlet Oxygen ◽  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Oxidative Detoxification ◽  
Organic Framework

scholarly journals A Singlet Oxygen Reservoir Based on Poly-Pyridone and Porphyrin Nanoscale Metal–Organic Framework for Cancer Therapy

CCS Chemistry ◽  
2020 ◽  
pp. 1187-1202
Author(s):  
Bo-Ru Xie ◽  
Chu-Xin Li ◽  
Yun Yu ◽  
Jin-Yue Zeng ◽  
Ming-Kang Zhang ◽  
...  
Keyword(s):  
Cancer Therapy ◽  
Singlet Oxygen ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Exploitation of missing linker in Zr-based metal-organic framework as the catalyst support for selective oxidation of benzyl alcohol

APL Materials ◽  
2019 ◽  
Vol 7 (11) ◽  
pp. 111109 ◽  
Author(s):  
Watthanachai Jumpathong ◽  
Taweesak Pila ◽  
Yuwanda Lekjing ◽  
Prae Chirawatkul ◽  
Bundet Boekfa ◽  
...  
Keyword(s):  
Benzyl Alcohol ◽  
Selective Oxidation ◽  
Metal Organic Framework ◽  
Catalyst Support ◽  
Oxidation Of Benzyl Alcohol ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Air oxidation of sulfur mustard gas simulants using a pyrene-based metal–organic framework photocatalyst

2019 ◽  
Vol 10 ◽  
pp. 2422-2427 ◽  
Author(s):  
Ghada Ayoub ◽  
Mihails Arhangelskis ◽  
Xuan Zhang ◽  
Florencia Son ◽  
Timur Islamoglu ◽  
...  
Keyword(s):  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Oxidative Degradation ◽  
Chemical Warfare Agents ◽  
Mustard Gas ◽  
Air Oxidation ◽  
Substitution Pattern ◽  
Warfare Agents ◽  
Metal Organic ◽  
Organic Framework

We demonstrate a microporous metal–organic framework NU-400 based on a 2,7-disubstituted pyrene linker as a highly efficient photosensitizer for generating singlet oxygen and subsequent oxidative degradation of chemical warfare agents (CWAs). The high activity of NU-400 permits photocatalytic conversion of the 2-chloroethyl ethyl sulfide (CEES) mustard gas simulant into a benign sulfoxide derivative, in air, with less than 15 minutes’ half-life. This is a considerable improvement to NU-1000, based on a 1,3,6,8-tetrasubstituted pyrene unit, demonstrating how variation of the substitution pattern of a metal–organic framework linker permits modification of its photoactive behavior.

Selective oxidation of tetralin over a chromium terephthalate metal organic framework, MIL-101

2009 ◽  
pp. 3904 ◽  
Author(s):  
Jun Kim ◽  
Samiran Bhattacharjee ◽  
Kwang-Eun Jeong ◽  
Soon-Yong Jeong ◽  
Wha-Seung Ahn
Keyword(s):  
Selective Oxidation ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework
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