Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal-Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard

2016 ◽  
Vol 23 (1) ◽  
pp. 214-218 ◽  
Author(s):  
Ashlee J. Howarth ◽  
Cassandra T. Buru ◽  
Yangyang Liu ◽  
Ann M. Ploskonka ◽  
Karel J. Hartlieb ◽  
...  
Keyword(s):  
Singlet Oxygen ◽  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Oxidative Detoxification ◽  
Organic Framework

scholarly journals Efficient and selective oxidation of sulfur mustard using singlet oxygen generated by a pyrene-based metal–organic framework

2016 ◽  
Vol 4 (36) ◽  
pp. 13809-13813 ◽  
Author(s):  
Yangyang Liu ◽  
Cassandra T. Buru ◽  
Ashlee J. Howarth ◽  
John J. Mahle ◽  
James H. Buchanan ◽  
...  
Keyword(s):  
Singlet Oxygen ◽  
Selective Oxidation ◽  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Uv Led ◽  
Metal Organic ◽  
Led Irradiation ◽  
Organic Framework

Singlet oxygen generated by a metal–organic framework under UV LED irradiation selectively oxidizes sulfur mustard to nontoxic products.

scholarly journals A Singlet Oxygen Reservoir Based on Poly-Pyridone and Porphyrin Nanoscale Metal–Organic Framework for Cancer Therapy

CCS Chemistry ◽  
2020 ◽  
pp. 1187-1202
Author(s):  
Bo-Ru Xie ◽  
Chu-Xin Li ◽  
Yun Yu ◽  
Jin-Yue Zeng ◽  
Ming-Kang Zhang ◽  
...  
Keyword(s):  
Cancer Therapy ◽  
Singlet Oxygen ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Air oxidation of sulfur mustard gas simulants using a pyrene-based metal–organic framework photocatalyst

2019 ◽  
Vol 10 ◽  
pp. 2422-2427 ◽  
Author(s):  
Ghada Ayoub ◽  
Mihails Arhangelskis ◽  
Xuan Zhang ◽  
Florencia Son ◽  
Timur Islamoglu ◽  
...  
Keyword(s):  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Oxidative Degradation ◽  
Chemical Warfare Agents ◽  
Mustard Gas ◽  
Air Oxidation ◽  
Substitution Pattern ◽  
Warfare Agents ◽  
Metal Organic ◽  
Organic Framework

We demonstrate a microporous metal–organic framework NU-400 based on a 2,7-disubstituted pyrene linker as a highly efficient photosensitizer for generating singlet oxygen and subsequent oxidative degradation of chemical warfare agents (CWAs). The high activity of NU-400 permits photocatalytic conversion of the 2-chloroethyl ethyl sulfide (CEES) mustard gas simulant into a benign sulfoxide derivative, in air, with less than 15 minutes’ half-life. This is a considerable improvement to NU-1000, based on a 1,3,6,8-tetrasubstituted pyrene unit, demonstrating how variation of the substitution pattern of a metal–organic framework linker permits modification of its photoactive behavior.

Kinetics of degradation of sulfur mustard and sarin simulants on HKUST-1 metal organic framework

2012 ◽  
Vol 41 (40) ◽  
pp. 12346 ◽  
Author(s):  
Anuradha Roy ◽  
Avanish K. Srivastava ◽  
Beer Singh ◽  
Dilip Shah ◽  
Timir Haran Mahato ◽  
...  
Keyword(s):  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Kinetics Of Degradation ◽  
Kinetics Of ◽  
Organic Framework

scholarly journals Protective Fabrics: Metal-Organic Framework Textiles for Rapid Photocatalytic Sulfur Mustard Simulant Detoxification

Matter ◽  
2020 ◽  
Vol 2 (2) ◽  
pp. 404-415 ◽  
Author(s):  
Dennis T. Lee ◽  
Jovenal D. Jamir ◽  
Gregory W. Peterson ◽  
Gregory N. Parsons
Keyword(s):  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Protective Fabrics ◽  
Organic Framework

Degradation of sulfur mustard and 2-chloroethyl ethyl sulfide on Cu–BTC metal organic framework

2012 ◽  
Vol 162 ◽  
pp. 207-212 ◽  
Author(s):  
Anuradha Roy ◽  
Avanish Kumar Srivastava ◽  
Beer Singh ◽  
T.H. Mahato ◽  
Dilip Shah ◽  
...  
Keyword(s):  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Detoxification of a Sulfur Mustard Simulant Using a BODIPY-Functionalized Zirconium-Based Metal–Organic Framework

2017 ◽  
Vol 9 (29) ◽  
pp. 24555-24560 ◽  
Author(s):  
Ahmet Atilgan ◽  
Timur Islamoglu ◽  
Ashlee J. Howarth ◽  
Joseph T. Hupp ◽  
Omar K. Farha
Keyword(s):  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Enabling photocatalytic activity of [Ru(2,2′:6′,2′′-terpyridine)2]2+ integrated into a metal–organic framework

2021 ◽  
Author(s):  
Dong Luo ◽  
Tao Zuo ◽  
Ji Zheng ◽  
Zi-Hao Long ◽  
Xue-Zhi Wang ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Singlet Oxygen ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

A multicomponent metal–organic framework is constructed to incorporate the bis-terpyridyl ruthenium motif, which was considered poorly photoactive, through a stepwise reticular synthesis to arouse its photosensitiveness for producing singlet oxygen.

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