scholarly journals Mild electrochemical synthesis of metal phosphides with dibenzo-7-phosphanorbornadiene derivatives: mechanistic insights and application to proton reduction in water

2018 ◽  
Vol 54 (7) ◽  
pp. 767-770 ◽  
Author(s):  
Naoki Shida ◽  
Joshua A. Buss ◽  
Theodor Agapie

Transition metal phosphide films were synthesized using a mild electrochemical method.


2019 ◽  
Vol 55 (60) ◽  
pp. 8744-8763 ◽  
Author(s):  
Wei Li ◽  
Dehua Xiong ◽  
Xuefei Gao ◽  
Lifeng Liu

Dynamic morphological, structural and compositional changes will occur when transition metal phosphides and chalcogenides are used to catalyze the oxygen evolution reaction, which can substantially enhance their electrocatalytic performance.



2015 ◽  
Vol 8 (10) ◽  
pp. 3022-3029 ◽  
Author(s):  
Jakob Kibsgaard ◽  
Charlie Tsai ◽  
Karen Chan ◽  
Jesse D. Benck ◽  
Jens K. Nørskov ◽  
...  

A volcano relationship exists between hydrogen evolution activities and hydrogen adsorption free energies for transition metal phosphides. We further predict and confirm that Fe0.5Co0.5P exhibits the highest activity.



2021 ◽  
Vol MA2021-01 (39) ◽  
pp. 1286-1286
Author(s):  
Brandi Cossairt ◽  
David Ung ◽  
Ian Murphy ◽  
Ricardo Rivera-Maldonado




2016 ◽  
Vol 8 (20) ◽  
pp. 12798-12803 ◽  
Author(s):  
Carlos G. Read ◽  
Juan F. Callejas ◽  
Cameron F. Holder ◽  
Raymond E. Schaak




2019 ◽  
Vol 21 (44) ◽  
pp. 24489-24498 ◽  
Author(s):  
Chenyang Li ◽  
Hao Gao ◽  
Wan Wan ◽  
Tim Mueller

Cluster expansions and Monte Carlo simulations provide insights into the mechanisms for the hydrogen evolution reaction and the effects of potential and surface coverage on Pt(111) and model transition metal phosphide surfaces.



2019 ◽  
Vol 7 (12) ◽  
pp. 7168-7178 ◽  
Author(s):  
Baicheng Weng ◽  
Xiaoming Wang ◽  
Corey R. Grice ◽  
Fenghua Xu ◽  
Yanfa Yan

A new metal–organic framework enables a facile and scalable synthesis of transition metal phosphide and sulfide nanoparticle encapsulated by heteroatom-doped carbon as bifunctional electrocatalysts for water splitting.



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