scholarly journals Synthesis of new hybrid 1,4-thiazinyl-1,2,3-dithiazolyl radicals via Smiles rearrangement

2017 ◽  
Vol 46 (46) ◽  
pp. 16004-16008 ◽  
Author(s):  
Petra Vasko ◽  
Juha Hurmalainen ◽  
Akseli Mansikkamäki ◽  
Anssi Peuronen ◽  
Aaron Mailman ◽  
...  
Keyword(s):  
Smiles Rearrangement ◽  
Spin Densities

New hybrid 1,4-thiazine-1,2,3-dithiazolylium salts were prepared via Smiles rearrangement. The cations can be readily reduced to the corresponding stable neutral radicals with delocalised spin densities.

Several Species of Nucleophiles in the Smiles Rearrangement

2017 ◽  
Vol 21 (16) ◽  
Author(s):  
Ali Ramazani ◽  
Farzaneh Moradnia ◽  
Hamideh Aghahosseini ◽  
Ilnaz Abdolmaleki
Keyword(s):  
Smiles Rearrangement

BENZOTHIAZEPINONES, RELATED COMPOUNDS, AND THE SMILES REARRANGEMENT

1979 ◽  
Vol 7 (1) ◽  
pp. 41-45 ◽  
Author(s):  
Edward Y Chan ◽  
Ronald G. Crampton ◽  
Leallyn B. Clapp
Keyword(s):  
Smiles Rearrangement ◽  
Related Compounds

Spin densities in CH2-(CH)3=CH2 radical

1962 ◽  
Vol 12 (11) ◽  
pp. 859-862 ◽  
Author(s):  
R. Lenk
Keyword(s):  
Spin Densities
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