scholarly journals Universal kinetic solvent effects in acid-catalyzed reactions of biomass-derived oxygenates

2018 ◽  
Vol 11 (3) ◽  
pp. 617-628 ◽  
Author(s):  
Theodore W. Walker ◽  
Alex K. Chew ◽  
Huixiang Li ◽  
Benginur Demir ◽  
Z. Conrad Zhang ◽  
...  
Keyword(s):  
Organic Solvent ◽  
Solvent Effects ◽  
Biomass Conversion ◽  
Molecular Simulations ◽  
Reaction Rates ◽  
Acid Catalyzed ◽  
Catalyzed Reactions

Experiments and molecular simulations are combined to understand organic solvent effects, enabling prediction of acid-catalyzed reaction rates for biomass conversion.

scholarly journals Solvent Effects in Acid-Catalyzed Biomass Conversion Reactions

2014 ◽  
Vol 126 (44) ◽  
pp. 12066-12069 ◽  
Author(s):  
Max A. Mellmer ◽  
Canan Sener ◽  
Jean Marcel R. Gallo ◽  
Jeremy S. Luterbacher ◽  
David Martin Alonso ◽  
...  
Keyword(s):  
Solvent Effects ◽  
Biomass Conversion ◽  
Acid Catalyzed

scholarly journals Correction: Universal kinetic solvent effects in acid-catalyzed reactions of biomass-derived oxygenates

2018 ◽  
Vol 11 (6) ◽  
pp. 1639-1639
Author(s):  
Theodore W. Walker ◽  
Alex K. Chew ◽  
Huixiang Li ◽  
Benginur Demir ◽  
Z. Conrad Zhang ◽  
...  
Keyword(s):  
Solvent Effects ◽  
Acid Catalyzed ◽  
Catalyzed Reactions ◽  
Energy Environ

Correction for ‘Universal kinetic solvent effects in acid-catalyzed reactions of biomass-derived oxygenates’ by Theodore W. Walker et al., Energy Environ. Sci., 2018, 11, 617–628.

Solvent effects in solid acid-catalyzed reactions: The case of the liquid-phase isomerization/cyclization of citronellal over SiO2-Al2O3

2020 ◽  
Vol 481 ◽  
pp. 110192 ◽  
Author(s):  
Nicolás M. Bertero ◽  
Andrés F. Trasarti ◽  
María C. Acevedo ◽  
Alberto J. Marchi ◽  
Carlos R. Apesteguía
Keyword(s):  
Liquid Phase ◽  
Solvent Effects ◽  
Solid Acid ◽  
Acid Catalyzed ◽  
Catalyzed Reactions

scholarly journals Solvent Effects in Acid-Catalyzed Biomass Conversion Reactions

2014 ◽  
Vol 53 (44) ◽  
pp. 11872-11875 ◽  
Author(s):  
Max A. Mellmer ◽  
Canan Sener ◽  
Jean Marcel R. Gallo ◽  
Jeremy S. Luterbacher ◽  
David Martin Alonso ◽  
...  
Keyword(s):  
Solvent Effects ◽  
Biomass Conversion ◽  
Acid Catalyzed

ChemInform Abstract: Organic Solvent Effects in Biomass Conversion Reactions

ChemInform ◽  
2016 ◽  
Vol 47 (12) ◽  
pp. no-no
Author(s):  
Li Shuai ◽  
Jeremy Luterbacher
Keyword(s):  
Organic Solvent ◽  
Solvent Effects ◽  
Biomass Conversion

The Solvent Effects on Kinetics and Mechanism of Zinc or Cadmium Halide Catalyzed Reactions of Hydrosilanes with Hydroxylic Reagents

2004 ◽  
Vol 69 (12) ◽  
pp. 2281-2296 ◽  
Author(s):  
Jerzy J. Chruściel
Keyword(s):  
Dielectric Constant ◽  
Solvent Effects ◽  
Kinetic Method ◽  
Kinetic Studies ◽  
Reaction Rates ◽  
Nucleophilic Catalysis ◽  
Effect Of Solvent ◽  
Cadmium Bromide ◽  
Catalyzed Reactions

The effect of solvent composition on reaction rates was studied by a kinetic method for reactions of Et3SiH with Ph2Si(OH)2 in the presence of ZnCl2 in a mixture of DMF and THF or Et3SiH with PhCOOH and cadmium bromide CdBr2 in DMF-1,4-dioxane and DMF-THF. A decrease in reaction rates with decreasing polarity of the medium (and its dielectric constant) has been observed. The kinetic order of dehydrocoupling reaction with respect to DMF was determined from kinetic studies. The constants of nucleophilic catalysis with DMF (λ) were found. The role of DMF in the mechanism of dehydrocoupling of hydrosilanes with hydroxylic reagents in the presence of ZnX2 and CdX2 halides (X = Cl, Br, I) is discussed.

scholarly journals Organic Solvent Effects in Biomass Conversion Reactions

ChemSusChem ◽  
2015 ◽  
Vol 9 (2) ◽  
pp. 133-155 ◽  
Author(s):  
Li Shuai ◽  
Jeremy Luterbacher
Keyword(s):  
Organic Solvent ◽  
Solvent Effects ◽  
Biomass Conversion

Kinetic Solvent Effects in Organic Reactions

2017 ◽  
Author(s):  
Belinda Slakman ◽  
Richard West
Keyword(s):  
Solvent Effect ◽  
Reaction Kinetics ◽  
Computational Methods ◽  
High Throughput ◽  
Kinetic Modeling ◽  
Solvent Effects ◽  
Reaction Rates ◽  
Prior Work ◽  
Solvent Phase ◽  
High Throughput Manner

<div> <div> <div> <p>This article reviews prior work studying reaction kinetics in solution, with the goal of using this information to improve detailed kinetic modeling in the solvent phase. Both experimental and computational methods for calculating reaction rates in liquids are reviewed. Previous studies, which used such methods to determine solvent effects, are then analyzed based on reaction family. Many of these studies correlate kinetic solvent effect with one or more solvent parameters or properties of reacting species, but it is not always possible, and investigations are usually done on too few reactions and solvents to truly generalize. From these studies, we present suggestions on how best to use data to generalize solvent effects for many different reaction types in a high throughput manner. </p> </div> </div> </div>

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