The effect of solvent relaxation time constants on free energy gap law for ultrafast charge recombination following photoinduced charge separation

Ultrafast low exergonic charge recombination following photoinduced charge separation proceeds in a non-equilibrium mode and its rate constant is nearly independent of the free energy gap.

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Intramolecular photoinduced charge separation and charge recombination of the product ion pair states of a series of fixed-distance dyads of porphyrins and quinones: energy gap and temperature dependences of the rate constants

Journal of the American Chemical Society ◽

10.1021/ja00066a036 ◽

1993 ◽

Vol 115 (13) ◽

pp. 5665-5674 ◽

Cited By ~ 102

Author(s):

Tsuyoshi Asahi ◽

Masaya Ohkohchi ◽

Ryohzi Matsusaka ◽

Noboru Mataga ◽

Run Ping Zhang ◽

...

Keyword(s):

Rate Constants ◽

Charge Separation ◽

Energy Gap ◽

Ion Pair ◽

Charge Recombination ◽

Fixed Distance ◽

Photoinduced Charge Separation ◽

Temperature Dependences ◽

Photoinduced Charge

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Theoretical study of the time-dependent energy gap law of photoinduced charge separation reactions in solution and examination of Collins-Kimball model

10.1063/1.45394 ◽

1994 ◽

Author(s):

T. Kakitani ◽

N. Matsuda ◽

T. Denda ◽

N. Mataga ◽

Y. Enomoto

Keyword(s):

Charge Separation ◽

Theoretical Study ◽

Energy Gap ◽

Time Dependent ◽

Energy Gap Law ◽

Photoinduced Charge Separation ◽

Photoinduced Charge

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Examination of the viability of the Collins-Kimball model and numerical calculation of the time-dependent energy gap law of photoinduced charge separation in polar solution

Chemical Physics ◽

10.1016/0301-0104(94)00317-4 ◽

1995 ◽

Vol 190 (1) ◽

pp. 83-95 ◽

Cited By ~ 40

Author(s):

Narifumi Matsuda ◽

Toshiaki Kakitani ◽

Takeshi Denda ◽

Noboru Mataga

Keyword(s):

Numerical Calculation ◽

Charge Separation ◽

Energy Gap ◽

Time Dependent ◽

Polar Solution ◽

Energy Gap Law ◽

Photoinduced Charge Separation ◽

Photoinduced Charge

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Energy-Gap Dependence of Photoinduced Charge Separation and Subsequent Charge Recombination in 1,4-Phenylene-Bridged Zinc-Free-Base Hybrid Porphyrins

Chemistry - A European Journal ◽

10.1002/(sici)1521-3765(20000103)6:1<33::aid-chem33>3.0.co;2-7 ◽

2000 ◽

Vol 6 (1) ◽

pp. 33-46 ◽

Cited By ~ 43

Author(s):

Atsuhiro Osuka ◽

Go Noya ◽

Seiji Taniguchi ◽

Tadashi Okada ◽

Yoshinobu Nishimura ◽

...

Keyword(s):

Charge Separation ◽

Energy Gap ◽

Charge Recombination ◽

Free Base ◽

Photoinduced Charge Separation ◽

Photoinduced Charge

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Dependence of rate constants for photoinduced charge separation and dark charge recombination on the free energy of reaction in restricted-distance porphyrin-quinone molecules

Journal of the American Chemical Society ◽

10.1021/ja00290a066 ◽

1985 ◽

Vol 107 (4) ◽

pp. 1080-1082 ◽

Cited By ~ 237

Author(s):

Michael R. Wasielewski ◽

Mark P. Niemczyk ◽

Walter A. Svec ◽

E. Bradley Pewitt

Keyword(s):

Free Energy ◽

Rate Constants ◽

Charge Separation ◽

Charge Recombination ◽

Photoinduced Charge Separation ◽

Photoinduced Charge

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ChemInform Abstract: DEPENDENCE OF RATE CONSTANTS FOR PHOTOINDUCED CHARGE SEPARATION AND DARK CHARGE RECOMBINATION ON THE FREE ENERGY OF REACTION IN RESTRICTED-DISTANCE PORPHYRIN-QUINONE MOLECULES

Chemischer Informationsdienst ◽

10.1002/chin.198527109 ◽

1985 ◽

Vol 16 (27) ◽

Author(s):

M. R. WASIELEWSKI ◽

M. P. NIEMCZYK ◽

W. A. SVEC ◽

E. B. PEWITT

Keyword(s):

Free Energy ◽

Rate Constants ◽

Charge Separation ◽

Charge Recombination ◽

Photoinduced Charge Separation ◽

Photoinduced Charge

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Photoinduced electron transfer in 5-bromouracil labeled DNA. A contrathermodynamic mechanism revisited by electron transfer theories

Physical Chemistry Chemical Physics ◽

10.1039/c8cp07700b ◽

2019 ◽

Vol 21 (8) ◽

pp. 4387-4393 ◽

Cited By ~ 3

Author(s):

Lorenzo Cupellini ◽

Paweł Wityk ◽

Benedetta Mennucci ◽

Janusz Rak

Keyword(s):

Electron Transfer ◽

Charge Separation ◽

Photoinduced Electron Transfer ◽

Charge Recombination ◽

Photoinduced Charge Separation ◽

Photoinduced Charge

Neither the rates of photoinduced charge separation nor charge recombination account for the substantial damage observed in the 5′-ABrU sequence.

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Dipole-Mediated Rectification of Intramolecular Photoinduced Charge Separation and Charge Recombination

Journal of the American Chemical Society ◽

10.1021/ja505618n ◽

2014 ◽

Vol 136 (37) ◽

pp. 12966-12973 ◽

Cited By ~ 31

Author(s):

Duoduo Bao ◽

Srigokul Upadhyayula ◽

Jillian M. Larsen ◽

Bing Xia ◽

Boriana Georgieva ◽

...

Keyword(s):

Charge Separation ◽

Charge Recombination ◽

Photoinduced Charge Separation ◽

Photoinduced Charge

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Photoinduced Charge-Separation and Charge-Recombination Processes of Oligo(thienyleneethynyl)–Fullerene Dyad Molecules

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.79.1860 ◽

2006 ◽

Vol 79 (12) ◽

pp. 1860-1868 ◽

Cited By ~ 1

Author(s):

Mamoru Fujitsuka ◽

Takashi Makinoshima ◽

Atushi Takamizawa ◽

Yasuyuki Araki ◽

Osamu Ito ◽

...

Keyword(s):

Charge Separation ◽

Charge Recombination ◽

Recombination Processes ◽

Photoinduced Charge Separation ◽

Photoinduced Charge

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Distance-Dependent Rates of Photoinduced Charge Separation and Dark Charge Recombination in Fixed-Distance Porphyrin-Quinone Molecules

ACS Symposium Series - Porphyrins ◽

10.1021/bk-1986-0321.ch011 ◽

1986 ◽

pp. 154-165 ◽

Cited By ~ 10

Author(s):

Michael R. Wasielewski ◽

Mark P. Niemczyk

Keyword(s):

Charge Separation ◽

Charge Recombination ◽

Fixed Distance ◽

Photoinduced Charge Separation ◽

Photoinduced Charge

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