scholarly journals Toward understanding the adsorption mechanism of large size organic corrosion inhibitors on an Fe(110) surface using the DFTB method

RSC Advances ◽  
2017 ◽  
Vol 7 (46) ◽  
pp. 29042-29050 ◽  
Author(s):  
Lei Guo ◽  
Chengwei Qi ◽  
Xingwen Zheng ◽  
Renhui Zhang ◽  
Xun Shen ◽  
...  
Keyword(s):  
Metal Surface ◽  
Corrosion Inhibitors ◽  
Adsorption Mechanism ◽  
Large Size ◽  
Organic Corrosion Inhibitors

Compared with the conventional DFT approach, SCC-DFTB method is more effective to deal with the adsorption issues of large size organic corrosion inhibitors on metal surface.

scholarly journals Terephthalohydrazide and isophthalo- hydrazide as new corrosion inhibitors for mild steel in hydrochloric acid: Experimental and theoretical approaches

2021 ◽  
Vol 65 (1) ◽  
pp. 12-22
Author(s):  
Shaimaa B. Al-Baghdadi ◽  
Ahmed A. Al-Amiery ◽  
Tayser S. Gaaz ◽  
Abdul Amir H. Kadhum
Keyword(s):  
Mild Steel ◽  
Quantum Chemical ◽  
Steel Surface ◽  
Corrosion Inhibitors ◽  
Adsorption Mechanism ◽  
Optimum Concentration ◽  
Chemical Adsorption ◽  
Theoretical Approaches ◽  
Polar Groups ◽  
Organic Corrosion Inhibitors

Abstract Most organic corrosion inhibitors have polar groups through which the molecule can be adsorbed strongly or specifically on the metal surface. In this investigation, terephthalo- hydrazide and isophthalohydrazide were synthesized as corrosion inhibitors, and their corrosion-inhibiting properties on mild steel were evaluated in a corrosive environment by weight loss measurements. The results of corrosion experiments revealed that terephthalohydrazide and isophthalohydrazide as inhibitors controlled or reduced corrosion through adsorption mechanism and showed inhibitive efficiencies of 96.4 % and 97.2 %, respectively, at the optimum concentration of 0.5 mM. The surface morphology of the metal was evaluated by scanning electron microscopy. The terephthalohydrazide or isophthalohydrazide molecules were adsorbed on the mild steel surface, and the process of adsorption follows chemical adsorption. Quantum chemical calculations of the tested corrosion inhibitors were consistent with the experimental observations.

Experimental and theoretical study of organic corrosion inhibitors on iron in acidic medium

1998 ◽  
Vol 41 (3) ◽  
pp. 501-517 ◽  
Author(s):  
M. Bouayed ◽  
H. Rabaa ◽  
A. Srhiri ◽  
J.-Y. Saillard ◽  
A.Ben Bachir ◽  
...  
Keyword(s):  
Acidic Medium ◽  
Corrosion Inhibitors ◽  
Theoretical Study ◽  
Organic Corrosion Inhibitors

scholarly journals Greener Approach towards Corrosion Inhibition

2013 ◽  
Vol 2013 ◽  
pp. 1-10 ◽  
Author(s):  
Neha Patni ◽  
Shruti Agarwal ◽  
Pallav Shah
Keyword(s):  
Heavy Metals ◽  
Amino Acids ◽  
Plant Extracts ◽  
Corrosion Inhibitors ◽  
Organic Dyes ◽  
Plant Origin ◽  
Toxic Compounds ◽  
Green Inhibitors ◽  
Protective Films ◽  
Organic Corrosion Inhibitors

Corrosion control of metals is technically, economically, environmentally, and aesthetically important. The best option is to use inhibitors for protecting metals and alloys against corrosion. As organic corrosion inhibitors are toxic in nature, so green inhibitors which are biodegradable, without any heavy metals and other toxic compounds, are promoted. Also plant products are inexpensive, renewable, and readily available. Tannins, organic amino acids, alkaloids, and organic dyes of plant origin have good corrosion-inhibiting abilities. Plant extracts contain many organic compounds, having polar atoms such as O, P, S, and N. These are adsorbed on the metal surface by these polar atoms, and protective films are formed, and various adsorption isotherms are obeyed. Various types of green inhibitors and their effect on different metals are mentioned in the paper.

Effect of Organic Corrosion Inhibitors on Corrosion Fatigue

CORROSION ◽  
1967 ◽  
Vol 23 (3) ◽  
pp. 65-71 ◽  
Author(s):  
PARVIZ MEHDIZADEH ◽  
R. L. McGLASSON ◽  
J. E. LANDERS
Keyword(s):  
Corrosion Fatigue ◽  
Diesel Fuel ◽  
Corrosion Inhibitors ◽  
Fatigue Cracks ◽  
Material Surface ◽  
Significant Protection ◽  
Inhibitor Concentration ◽  
Degree Of Protection ◽  
Organic Inhibitors ◽  
Organic Corrosion Inhibitors

Abstract The effect of organic inhibitors on corrosion fatigue performance of steel in a mixture of brine containing H2S-CO2 and diesel fuel is reported. The inhibitor concentration required to give significant protection to steel under corrosion fatigue conditions is much higher than that for corrosion control. This is due to the fact that corrosion fatigue cracks initiated at incompletely protected spots on the material surface influence fatigue failure regardless of the degree of protection achieved on neighboring areas. Effects of fatigue stress and concentration of corrosion inhibitors were investigated. Results were analyzed in terms of the proposed mechanism for corrosion inhibition in these environments.

scholarly journals Experimental and theoretical investigations of four amine derivatives as effective corrosion inhibitors for mild steel in HCl medium

RSC Advances ◽  
2020 ◽  
Vol 10 (40) ◽  
pp. 24145-24158 ◽  
Author(s):  
Yasmine Boughoues ◽  
Messaoud Benamira ◽  
Lyamine Messaadia ◽  
Nafila Bouider ◽  
Samia Abdelaziz
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibitors ◽  
Amine Derivative ◽  
Theoretical Investigations ◽  
Organic Corrosion Inhibitors ◽  
Hcl Medium

Four amine derivative compounds were synthesized and used as organic corrosion inhibitors.

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