scholarly journals A phosphine-free, atom-efficient cross-coupling reaction of triorganoindiums with acyl chlorides catalyzed by immobilization of palladium(0) in MCM-41

RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42570-42578 ◽  
Author(s):  
Jiankang Miao ◽  
Bin Huang ◽  
Haiyi Liu ◽  
Mingzhong Cai
Keyword(s):  
Schiff Base ◽  
Schiff Base Complex ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Free Atom ◽  
Acyl Chlorides ◽  
Base Complex ◽  
Cross Coupling Reaction ◽  
Mcm 41

The phosphine-free, atom-efficient cross-coupling of triorganoindiums with acyl chlorides has been achieved using a recyclable MCM-41-immobilized palladium(0)–Schiff base complex.

scholarly journals Synthesis, Characterization and Catalytic Activity of Nano-Iron (II) Schiff Base Complex in Suzuki-Miyaura Cross Coupling Reaction

2018 ◽  
Vol 7 (4.5) ◽  
pp. 435
Author(s):  
Rasheeda M. Ansari ◽  
Badekai Ramachandra Bat
Keyword(s):  
Particle Size ◽  
Schiff Base ◽  
Catalytic Activity ◽  
Schiff Base Complex ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Particle Size Analysis ◽  
Size Analysis ◽  
Base Complex ◽  
Cross Coupling Reaction

A new nano-iron (II) Schiff base complex, [Fe(L)] where L is 1-((pyridin-2-ylimino)methyl)naphthalen-2-ol with octahedral geometry has been synthesized by the sonochemical (Ultrasonic irradiation) method. This method can promote the formation of nano-sized particles in short time with improved yield toward conventional method. The complex was characterized by FTIR, UV-Vis, TGA, SEM and elemental analysis. Particle size of synthesized complex was calculated from particle size analysis. Catalytic activity of the prepared complex was studied for Suzuki-Miyaura cross-coupling reaction. The synthesized complex showed great potential in catalytic activity with less concentration. 

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